Direct (hetero) arylation: a new tool for polymer chemists

LG Mercier, M Leclerc - Accounts of chemical research, 2013 - ACS Publications
The coupling of aryl halides with catalytically activated aryl C–H bondsprovides a desirable
and atom-economical alternative to standard cross-coupling reactions for the construction of …

Metal-free, visible-light-mediated direct C–H arylation of heteroarenes with aryl diazonium salts

DP Hari, P Schroll, B König - Journal of the American Chemical …, 2012 - ACS Publications
Visible light along with 1 mol% eosin Y catalyzes the direct C–H bond arylation of
heteroarenes with aryl diazonium salts by a photoredox process. We have investigated the …

Microwave-assisted polycondensation via direct arylation of 3, 4-ethylenedioxythiophene with 9, 9-dioctyl-2, 7-dibromofluorene

SJ Choi, J Kuwabara, T Kanbara - ACS Sustainable Chemistry & …, 2013 - ACS Publications
For synthesis of π-conjugated polymers, polycondensation via direct arylation reactions of C–
H bonds in aromatic monomers with dibromo-arylenes has attracted increasing attention as …

C–H arylation reactions through aniline activation catalysed by a PANI-gC 3 N 4-TiO 2 composite under visible light in aqueous medium

L Wang, J Shen, S Yang, W Liu, Q Chen, M He - Green Chemistry, 2018 - pubs.rsc.org
A PANI (polyaniline)-g-C3N4-TiO2 composite was prepared and found to be efficient for
radical C–H arylation reactions. The arylation process involved coupling of in situ generated …

Strategic Advances in Sequential C-Arylations of Heteroarenes

S Cardoza, MK Shrivash, P Das… - The Journal of Organic …, 2020 - ACS Publications
Sequence-specific C-arylation strategies have important applications in medicinal and
material research. These strategies allow C–C bond formations in a regioselective manner …

Visible‐Light‐Photocatalyzed Metal‐Free C–H Heteroarylation of Heteroarenes at Room Temperature: A Sustainable Synthesis of Biheteroaryls

P Maity, D Kundu, BC Ranu - European Journal of Organic …, 2015 - Wiley Online Library
An efficient C–H heteroarylation of heteroarenes is achieved through visible‐light
photoredox‐catalyzed diazotization of heteroarylamines in situ by tBuONO at room …

NADH coenzyme model compound as photocatalyst for the direct arylation of (hetero) arenes

YS Feng, XS Bu, B Huang, C Rong, JJ Dai, J Xu… - Tetrahedron …, 2017 - Elsevier
Dihydro-10-methylacridine (AcrH 2), a NADH coenzyme model compound, as an organo-
photoredox catalyst is demonstrated for the cross-coupling of aryl diazonium salts with …

Solvent‐Controlled C2/C5‐Regiodivergent Alkenylation of Pyrroles

Y Su, S Gao, Y Huang, A Lin… - Chemistry–A European …, 2015 - Wiley Online Library
Abstract A solvent‐controlled C2/C5‐selective alkenylation of 3, 4‐disubstituted pyrroles has
been developed. The C3 substituent of pyrroles proved crucial to the regioselectivity …

Palladium-Catalyzed direct C–H arylation of 3-(methylsulfinyl) thiophenes

H Jiang, A Bellomo, M Zhang, PJ Carroll… - Organic …, 2018 - ACS Publications
A palladium-catalyzed direct arylation of (3-thiophene) S (O) Me derivatives has been
developed. This protocol is effective for the selective synthesis of 2-arylated and 2, 5 …

Isoquinoline Derivatives via Stepwise Regioselective sp2 and sp3 C–H Bond Functionalizations

T Boudiar, Z Sahli, B Sundararaju… - The Journal of …, 2012 - ACS Publications
Efficient and practically attractive stepwise ruthenium-and palladium-catalyzed
regioselective C–H bond functionalizations were achieved to produce 4-substituted …