Applications of TEMPO in Synthesis

T Vogler, A Studer - Synthesis, 2008 - thieme-connect.com
This review describes the broad application of TEMPO and its derivatives in organic
synthesis. Various reactions including oxidation of alcohols, sulfides and organometallic …

Three characteristic reactions of organocobalt compounds in organic synthesis

I Omae - Applied Organometallic Chemistry, 2007 - Wiley Online Library
Organocobalt compounds in organic synthesis have three characteristic reactions. The first
occurs because cobalt has a high affinity to carbon–carbon π‐bonds or carbon–nitrogen π …

Nitroxide radicals: properties, synthesis and applications

H Karoui, F Le Moigne, O Ouari… - … and applied aspects of …, 2010 - books.google.com
Since 1990, more than 4000 papers have appeared dealing with the synthesis, the
physicochemical properties, and the applications of stable nitroxides and molecules …

A concise formal synthesis of (−)-hamigeran B

B Jiang, M Li, P Xing, Z Huang - Organic letters, 2013 - ACS Publications
A concise and efficient formal synthesis of (−)-hamigeran B is reported. The critical
intermediate was synthesized from 3-methoxy-5-methylphenyl trifluoromethanesulfonate …

Reactivity of TEMPO toward 16-and 17-electron organometallic reaction intermediates: a time-resolved IR study

JP Lomont, SC Nguyen, CB Harris - Journal of the American …, 2013 - ACS Publications
The (2, 2, 6, 6-tetramethylpiperidin-1-yl) oxyl radical (TEMPO) has been employed for an
extensive range of chemical applications, ranging from organometallic catalysis to serving …

Reactivity of organothorium complexes with TEMPO

RR Langeslay, JR Walensky, JW Ziller… - Inorganic …, 2014 - ACS Publications
Reactions of the 2, 2, 6, 6-tetramethylpiperidin-1-oxyl radical (TEMPO) with thorium
metallocenes have been examined to investigate both the radical reaction patterns for …

A novel synthesis of fluorine-containing cyclopentenones via Pauson–Khand reaction

T Konno, T Kida, A Tani, T Ishihara - Journal of Fluorine Chemistry, 2012 - Elsevier
Intermolecular Pauson–Khand reaction of fluoroalkylated alkynes with 2-norbornene or 2, 5-
norbornadiene at the reflux temperature of dichloroethane proceeded smoothly to give the …

Selected recent developments in organo-cobalt chemistry

CJ Scheuermann, BD Ward - New Journal of Chemistry, 2008 - pubs.rsc.org
Organometallic complexes of cobalt continue to find application in a wide variety of contexts,
from fundamental organometallic and coordination chemistry, to the metal-mediated …

Radicals in transition metal catalyzed reactions? Transition metal catalyzed radical reactions? A fruitful interplay anyway: Part 1. Radical catalysis by group 4 to group …

U Jahn - Radicals in Synthesis III, 2012 - Springer
This review summarizes the current status of radical-based transition metal catalyzed
reactions in organic chemistry. The underlying features of radical generation from transition …

Nitroxide-catalyzed selective oxidation of alcohols and polysaccharides

IY Ponedel'kina, EA Khaibrakhmanova… - Russian Chemical …, 2010 - iopscience.iop.org
Nitroxide-catalyzed selective oxidation of alcohols and polysaccharides Page 1 Russian
Chemical Reviews Nitroxide-catalyzed selective oxidation of alcohols and polysaccharides To …