Trivalent aluminium compounds are well known for their reactivity as Lewis
acids/electrophiles, a feature that is exploited in many pharmaceutical, industrial and …

Synthetic routes to lithium, magnesium, and zinc aluminyl complexes are reported, allowing
for the first structural characterization of an unsupported lithium–aluminium bond …

The topic of heavier main group compounds possessing multiple bonds is the subject of
momentous interest in modern organometallic chemistry. Importantly, there is an excitement …

This work describes the synthesis and coordination behavior of a new mixed‐donor ligand
PhC (NtBu) 2SiC6H4PPh2 (1) containing both silylene and phosphine donor sites. Ligand 1 …

The activation of small molecules by silylenes bearing unique electronic properties has
been well established in the past few decades. Here, we disclose the reactivity study of …

Herein we report stable silicon-boron radicals of composition LSi (NMe2)–B (Br) Tip (1), LSi
(NMe2)–B (I) Tip (2) LSi (tBu)–B (I) Tip (3)[L= PhC (NtBu) 2]. They were prepared in high …

The reactions of the pyridine-functionalized silylene LNSi [L= PhC (N t Bu) 2; N= 2-
(methylamido) pyridine] with zinc and cadmium halides are described. These resulted in the …

The stable ferrocene‐based N‐heterocyclic silylenes fc [(N {B}) 2Si](A; fc= 1, 1'‐
ferrocenylene,{B}=(HCNDipp) 2B, Dipp= 2, 6‐diisopropylphenyl) and fc [(NDipp) 2Si](B) are …

MesP (H) SiCl2Ph (Mes= 2, 4, 6‐Me3C6H2)(7) with a reactive Si–Cl and P–H bond can
easily be reduced by KC8 or alternatively by a carbene to give remarkable phosphorus …

The one‐pot reaction of L1SiCl (L1= PhC (NtBu) 2) with MesPX2/IsPX2 (X= Cl, Br; Is= 2, 4, 6‐
iPr3C6H2, Mes= 2, 4, 6‐Me3C6H2) in the presence of KC8 yielded two phosphasilene …