The future of solution processing toward organic semiconductor devices: a substrate and integration perspective

S Wang, L Peng, H Sun, W Huang - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
π-Conjugated organic semiconductors (OSCs) are the basic scaffold of organic
semiconductor devices. Solution processing is an effective way to promote the …

Structure–function relationships in aryl diazirines reveal optimal design features to maximize C–H insertion

SF Musolino, Z Pei, L Bi, GA DiLabio, JE Wulff - Chemical Science, 2021 - pubs.rsc.org
Diazirine reagents allow for the ready generation of carbenes upon photochemical, thermal,
or electrical stimulation. Because carbenes formed in this way can undergo rapid insertion …

Design, Exploitation, and Rational Improvements of Diazirine-Based Universal Polymer Crosslinkers

ML Lepage, SF Musolino, JE Wulff - Accounts of Chemical …, 2024 - ACS Publications
Conspectus Addition of new covalent bonds between the chains of thermoplastic polymers
(ie, crosslinking) provides improved mechanical strength and enhanced high-temperature …

A cleavable crosslinking strategy for commodity polymer functionalization and generation of reprocessable thermosets

L Bi, B Godwin, MJ Baran, R Nazir… - Angewandte …, 2023 - Wiley Online Library
Covalently crosslinked polymeric materials, known as thermosets, possess enhanced
mechanical strength and thermal stability relative to the corresponding uncrosslinked …

Flexible polyfluorinated bis-diazirines as molecular adhesives

C Simhadri, L Bi, ML Lepage, M Takaffoli, Z Pei… - Chemical …, 2021 - pubs.rsc.org
Motivated by a desire to develop flexible covalent adhesives that afford some of the same
malleability in the adhesive layer as traditional polymer-based adhesives, we designed and …

Carbene-Based Bioadhesive Blended with Amine, Thiol, and Acrylate Liquid Additives

E Ellis, I Djordjevic, MN Bin Mohd Ali… - ACS Applied Polymer …, 2023 - ACS Publications
Light-activated carbenes provide a unique method of non-specific covalent bond formation
needed in bioadhesives and rapid gelation. The highly reactive carbenes formed upon UV …

Electronically optimized diazirine-based polymer crosslinkers

SF Musolino, M Mahbod, R Nazir, L Bi, HA Graham… - Polymer …, 2022 - pubs.rsc.org
Topical application of diazirine-based crosslinkers can upgrade the mechanical properties
of low-functionality commodity plastics by engaging in rapid C–H insertions along the …

Effect of bis-diazirine-mediated photo-crosslinking on polyvinylcarbazole and solution-processed polymer LEDs

K Dey, S Roy Chowdhury, E Dykstra… - ACS Applied …, 2021 - ACS Publications
The problems with fabrication of solution-processed organic light-emitting diodes (OLEDs)
stem largely from the defects associated with sequential deposition of the layers, solvent …

Polyamine–diazirine conjugates for use as primers in UHMWPE–epoxy composite materials

R Nazir, L Bi, SF Musolino, OH Margoto… - ACS Applied Polymer …, 2022 - ACS Publications
Ultra-high-molecular weight polyethylene (UHMWPE) fibers show promise for use in fiber-
reinforced polymer composites but have poor interfacial adhesion to the epoxy resin that …

Sandwich‐Like Encapsulation of a Highly Luminescent Copper (I) Complex

M Matejdes, M Stöter, R Czerwieniec… - Advanced Optical …, 2021 - Wiley Online Library
A small molecular weight cationic copper (I) complex showing high luminescence quantum
yield based on a thermally activated delayed fluorescence mechanism is immobilized …