Hydrosilanes are used as versatile coreactants in the generation of silyl-metal complexes.
Since organohydrosilanes may contain one, two, or three SiH bonds as tertiary, secondary …

This article provides an account of the group 10 transition-metal complexes with metal–
silicon bonds formed by the reaction of hydrosilanes with group 10 transition-metal …

Formally hexavalent palladium complexes have been isolated and structurally characterized
for the first time. Thermal condensation reaction of three molecules of 1, 2-C6H4 (SiH2) …

Alkyl, silyl, and phosphane ligands are amongst the most familiar and ubiquitous ligands in
organometallic and coordination chemistry. The C, Si, and P donor atoms of these ligands …

Pd and Ni dimers supported by PSiP ligands in which two hypervalent five‐coordinate Si
atoms bridge the two metal centers are reported. Crystallographic characterization revealed …

Divalent palladium-induced homocoupling of terminal zinc hydrides to zinc–zinc bonded
complexes was achieved herein. Reactions of zinc hydrides [L ZnH](L= CH3C (2, 6-i …

The reaction of tertiary silanes with the low valent palladium complex [(μ-dcpe) Pd] 2 affords
equilibrium mixtures with mononuclear silyl palladium hydrides. These complexes have …

Dinuclear Pt− Si complexes,[(Ph3P) Pt (μ-η 2-H− SiHAr)] 2 (Ar= 2-isopropyl-6-methylphenyl
(IMP), 2, 4, 6-trimethoxyphenyl (TMP), 2, 4, 6-trimethylphenyl (Mes), pentaphenylphenyl …

Experimental techniques for the measurement of 29 Si nmr spectra (mainly for solutions) are
briefly discussed, followed from considerations of the nuclear-spin relaxation mechanisms …

The reaction of Pt (SiHPh2) 2 (dmpe)(dmpe= 1, 2-bis (dimethylphosphino) ethane) with Pd
(PCy3) 2 forms (Cy3P) Pd (μ-η2-HSiPh2) 2Pt (PCy3)(1), which contains two diphenylsilyl …