The C− N bond is one of the most abundant chemical bonds and widely exists in many
organic molecules and biomacromolecules. The formation and transformation of C− N …

Transition metal-catalyzed cyclization reactions of unsaturated substrates have become one
of the most important and useful methodologies for the preparation of heterocycles. To this …

Herein, we report the additive-controlled divergent synthesis of tetrasubstituted 1, 3-enynes
and alkynylated 3 H-pyrrolo [1, 2-a] indol-3-ones through rhodium-catalyzed C–H …

Published data of the last 10 years concerning the development of new and upgrading of
known approaches to indole synthesis are integrated and analyzed. Modern versions of the …

An efficient Rh (III)-catalyzed C–H alkenylation/directing group migration cascade between
indoles and alkynes for the assembly of tetrasubstituted alkenes is reported. The carbamoyl …

Herein, we report the divergent synthesis of alkynylated imidazo [1, 5-a] indoles and α, α-
difluoromethylene tetrasubstituted alkenes through Rh (III)-catalyzed [4+ 1] …

A convenient and effective method of ruthenium‐catalyzed C− H/N− H annulations using
vinylene carbonate as oxidizing acetylene surrogate has been disclosed. This method is …

A Ni-catalyzed reaction was developed for the synthesis of multifunctionalized indoles. The
reaction proceeded through oxidative cyclization of the Ni (0)/P^ N complex with an enyne …

A one-pot protocol for the dearomatizing spirocyclization/cross-coupling of alkyne-tethered
indoles/pyrroles is described. Mechanistic studies support a process by which palladium …

The high mechanical strength and thermal resistance of an epoxy (EP) thermoset make it
ideal for wide applications in industries such as energy, aerospace, electronics, and …