Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Transition metal complexes with bulky 4, 6-di-tert-butyl-N-aryl (alkyl)-o-iminobenzoquinonato ligands: Structure, EPR and magnetism

AI Poddel'sky, VK Cherkasov, GA Abakumov - Coordination Chemistry …, 2009 - Elsevier
Coordination compounds based on the substituted o-iminoquinonato, o-
iminosemiquinonato and o-amidophenolato ligands with transition metal ions are described …

Toward molecular magnets: the metal-radical approach

A Caneschi, D Gatteschi, R Sessoli… - Accounts of Chemical …, 1989 - ACS Publications
Conclusions Acyl group transfer reactions in solution should not be assumed to involve only
addition or associative in-termediates in their mechanisms. Discussion of mech-anism for …

Unique properties of transition metal quinone complexes of the MQ3 series

CG Pierpont - Coordination Chemistry Reviews, 2001 - Elsevier
Transition metal complexes of ligands derived from o-benzoquinones have been shown to
exhibit unique versatility in their electronic, structural and magnetic properties. Examples of …

[图书][B] Magnetic molecular materials

D Gatteschi, O Kahn, JS Miller, F Palacio - 2012 - books.google.com
One of the major challenges of science in the last few years of the second millennium is
learning how to design materials which can fulfill specific tasks. Ambitious as it may be, the …

Crystal structure and magnetic properties of [Ln2Cu4] hexanuclear clusters (where Ln= trivalent lanthanide). Mechanism of the gadolinium (III)-copper (II) magnetic …

M Andruh, I Ramade, E Codjovi, O Guillou… - Journal of the …, 1993 - ACS Publications
In the past two decades or so, a large number of heteropoly-metallic compounds have been
described. The studies of these compounds have often been performed either in relation to …

The chemistry and magnetic properties of metal nitronyl nitroxide complexes

A Caneschi, D Gatteschi, P Rey - Prog. Inorg. Chem, 1991 - books.google.com
METAL NITRONYL NITROXIDE COMPLEXES 333 first can be the understanding of the
fundamental bonding interactions between the unpaired electrons of the radicals with the …

Ligand Modifications Produce Two‐Step Magnetic Switching in a Cobalt (dioxolene) Complex

K Kc, T Woods, L Olshansky - Angewandte Chemie, 2023 - Wiley Online Library
Mononuclear monodioxolene valence tautomeric (VT) cobalt complexes typically exist in
their low spin (ls) CoIII (cat2−) and high spin (hs) CoII (sq⋅−) forms (cat2−= catecholato, and …

Layered magnetic structure of a metal cluster ion

D Gatteschi, L Pardi, AL Barra, A Müller, J Döring - Nature, 1991 - nature.com
THE ability of molecular materials to perform many of the optical, electronic and magnetic
functions traditionally associated with extended two-and three-dimensional inorganic …

Nitrogen-bonded copper (II)-imino nitroxide complexes exhibiting large ferromagnetic interactions

D Luneau, P Rey, J Laugier, P Fries… - Journal of the …, 1991 - ACS Publications
The magnetic interactions between copper (II) and iminonitroxide free radicals have been
investigated in two novel adducts of copper (II)-bis (hexafluoroacetylacetonato): $(µ-1, 3-(2 …