Recent advances of propiolic acids in organic reactions

C Chen, J Wu, G Yan, D Huang - Tetrahedron Letters, 2020 - Elsevier
Herein, recent advances of propiolic acids in decade (2009–2019) were summarized as five
pathways according to their triggered mechanisms:(1) acids as nucleophiles;(2) electrophilic …

Larvicidal activity and in silico studies of cinnamic acid derivatives against Aedes aegypti (Diptera: Culicidae)

SB França, LCB de Lima, CR da Silva Cunha… - Bioorganic & Medicinal …, 2021 - Elsevier
Cinnamic acid derivatives (CAD's) represent a great alternative in the search for insecticides
against Aedes aegypti mosquitoes since they have antimicrobial and insecticide properties …

Catalyst-Free α-trans-Selective Hydroboration and (E)-Selective Deuterated Semihydrogenation of Alkynyl Sulfones

Y Duan, Z Zheng, Z Yu, S Sun, B Lin… - The Journal of Organic …, 2024 - ACS Publications
Here, we present a straightforward α-trans-selective hydroboration of alkynyl sulfones with
NHC–boranes without the need for a catalyst. This reaction is compatible with a wide range …

Development of α-acyloxycarboxamides targeting Leishmania amazonensis parasite

SB França, JE da Silva, LR Silva, EKA Padilha… - New Journal of …, 2024 - pubs.rsc.org
Leishmaniases comprise a set of neglected diseases, afflicting over one million people
worldwide and frequently leading to fatal outcomes, mainly in their visceral form. The current …

Catalytic, Transition-Metal-Free Semireduction of Propiolamide Derivatives: Scope and Mechanistic Investigation

RJ Grams, CJ Garcia, C Szwetkowski, WL Santos - Organic letters, 2020 - ACS Publications
We report a transition-metal-free trans-selective semireduction of alkynes with
pinacolborane and catalytic potassium tert-butoxide. A variety of 3-substituted primary and …

trans-Selective hydrocyanation of ynoates, ynones and ynoic acids catalyzed by nucleophilic phosphines

F Schömberg, M Perić, M Meyer, I Vilotijević - Tetrahedron, 2021 - Elsevier
Abstract trans-Selective hydrocyanation of ynoates and ynones in the presence of TMSCN
and an alcohol additive are catalyzed by nucleophilic phosphines. The trisubstituted E-olefin …

Oxidation and Reduction

RN Mehrotra - Organic Reaction Mechanisms· 2017: An annual …, 2020 - Wiley Online Library
Summary This Chapter Contains Sections titled: Reviews, Accounts, and Highlights
Oxidation and Reduction by Metal Ions and Related Species Chromium, Manganese, and …