Adsorption of Aromatic Molecules in a Microporous Spin Crossover Material, Fe(pyrazine)[Fe(CN)5NO]. Tuning of Its Physical Properties
In microporous materials, the guest species interacts with the host framework and can
modify the electronic structure of that last one and the related physical and functional …
modify the electronic structure of that last one and the related physical and functional …
Effect of CS2 and CO2 adsorption on the thermally-induced spin crossover in ferrous nitroprussides. Nature of the guest-host interactions
Tuning physical and functional properties in porous solids by introducing guest species in
their framework is an attractive research area in functional materials. Such a possibility is …
their framework is an attractive research area in functional materials. Such a possibility is …
Spin crossover in Hofmann-like coordination polymers. Effect of the axial ligand substituent and its position
This contribution reports the preparation and thermally induced spin crossover (SCO) in the
Hofmann-like Fe (3-hydroxypyridine) 2 [M (CN) 4] series, where M= Ni, Pd, and Pt. These …
Hofmann-like Fe (3-hydroxypyridine) 2 [M (CN) 4] series, where M= Ni, Pd, and Pt. These …
Thermally-induced spin-crossover (SCO) in Fe (4-ethynylpyrdine) 2 [Fe (CN) 5 NO]. Why is the SCO observed in 2D ferrous nitroprussides despite the NO–NC …
Pillared ferrous nitroprussides form an interesting series of coordination polymers where the
spin crossover (SCO) behavior has been observed for several pillar organic molecules. This …
spin crossover (SCO) behavior has been observed for several pillar organic molecules. This …
Interpenetration Phenomena via Anion Template Effects in Fe (II) and Co (II) Coordination Networks with a Bis-(1, 2, 4-triazole) Ligand
DN Jordan, PG Straßburg, D Woschko, LM Carrella… - Polymers, 2023 - mdpi.com
Seven new coordination networks,[Fe (tbbt) 3](BF4) 2 (1),[Co (tbbt) 3](BF4) 2 (2),[Fe (tbbt)
3](ClO4) 2 (3),[Co (tbbt) 3](ClO4) 2 (4),[Fe (NCS) 2 (tbbt) 2](5),[Co (NCS) 2 (tbbt) 2](6), and …
3](ClO4) 2 (3),[Co (tbbt) 3](ClO4) 2 (4),[Fe (NCS) 2 (tbbt) 2](5),[Co (NCS) 2 (tbbt) 2](6), and …
Fe(L)2[M(CN)4] with L = 4-Ethyl Isonicotinate and M = Ni, Pd, Pt.─A Series of Hofmann-Type Frameworks with Spin Crossover: The Dominant Role of the Fe–NC …
This contribution reports the incorporation of an organic pillar (L), 4-ethyl isonicotinate,
between adjacent layers of the series of 2D coordination polymers, Fe [M (CN) 4], with M …
between adjacent layers of the series of 2D coordination polymers, Fe [M (CN) 4], with M …
Spin-crossover in [Fe (Quinazoline) 2][Fe (CN) 5NO]. Evidence of its framework flexibility
The titled material shows a thermally induced spin-crossover (SCO) in the 75–150 K
temperature region, with a narrow hysteresis of about 3 K. The recorded DSC data show a …
temperature region, with a narrow hysteresis of about 3 K. The recorded DSC data show a …
The role of intermolecular interactions in [Fe (X-salEen) 2] ClO 4 spin crossover complexes
MA Bento, T Gomes, FF Martins, A Gil, LP Ferreira… - Dalton …, 2024 - pubs.rsc.org
Two new spin crossover (SCO) Fe (III) compounds were prepared, their structures were
analysed and their magnetic properties were investigated. An exhaustive analysis of the …
analysed and their magnetic properties were investigated. An exhaustive analysis of the …
Crystal structures and properties of Fe(H2O)2[Ni(CN)4]·nH2O hydrates
L Torres, AA Lemus-Santana, L Sánchez… - Journal of …, 2023 - Taylor & Francis
We report the crystal structures and properties of iron hydrate compounds. These hydrates
have 2D topologies and crystallize with three different structural features depending on the …
have 2D topologies and crystallize with three different structural features depending on the …