This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

The use of transition metals in cross‐coupling reactions has been verified as a powerful tool
in synthetic organic chemistry to access valuable pharmaceutical intermediates and …

Copper( ii )-mediated oxidative cyclization of enamides to oxazoles - Organic & Biomolecular
Chemistry (RSC Publishing) DOI:10.1039/C2OB25310K Royal Society of Chemistry View PDF …

An efficient hydroamidation of benzylamides with internal alkynes catalyzed by Ru (II) has
been developed. Various (E)-enamides were afforded in up to 95% yield for 28 examples …

Two novel compounds including a cyclohelminthol type polyketide (namely oxaleimide K, 1)
and a maleimide derivative (namely peniroquefortine A, 2), and a new natural product …

The total syntheses of lansiumamide A, lansiumamide B and alatamide have been
completed taking advantage of the dihalo-olefination of N-formylimides. The syntheses are …

Full details of the total synthesis of pacidamycin D (4) and its 3′-hydroxy analogue 32 are
described. The chemically labile Z-oxyacyl enamide moiety is the most challenging chemical …

In our efforts to probe the reaction mechanism of the endo cycloisomerization of alkynols
catalyzed by the complex [Ru (N3P)(OAc)](BPh4)(1; NP3= N, N-bis [(pyridin-2-yl) methyl][2 …

Divergent reactions between alkynes and dibenzenesulfonimide that can generate
ynamides and enamides selectively are reported. Oxidative C (sp)− H bond amidation of …

A novel protocol has been developed for the synthesis of N-aryl amides from
arenediazonium salts and primary amides. Tetrabutylammonium iodide was used as an …