Synthesis and Applications of 5‐Membered Chalcogen‐Nitrogen π‐Heterocycles with Three Heteroatoms

OA Rakitin, AV Zibarev - Asian Journal of Organic Chemistry, 2018 - Wiley Online Library
The recent progress in the synthesis of the title heterocycles exemplified by closed‐and
open‐shell 1, 2, 5‐chalcogenadiazoles, 1, 2, 3‐dichalcogenazoles and their hybrids …

Herz radicals: chemistry and materials science

YM Volkova, AY Makarov, EA Pritchina… - Mendeleev …, 2020 - Elsevier
Chemistry and materials science of Herz radicals (1, 2, 3-benzodichalcogenazolyls;
chalcogen is S or Se) are discussed including their synthesis, structure and reactivity …

Magnetic ordering and anisotropy in heavy atom radicals

SM Winter, S Hill, RT Oakley - Journal of the American Chemical …, 2015 - ACS Publications
Recent developments in stable radical chemistry have afforded “heavy atom” radicals,
neutral open-shell (S= 1/2) molecular species containing heavy p-block elements (S, Se) …

Importance of spin-orbit coupling in layered organic salts

SM Winter, K Riedl, R Valenti - Physical Review B, 2017 - APS
We investigate the spin-orbit coupling (SOC) effects in α-and κ-phase BEDT-TTF and BEDT-
TSF organic salts. Contrary to the assumption that SOC in organics is negligible due to light …

Magnetic fingerprint of individual Fe4 molecular magnets under compression by a scanning tunnelling microscope

JAJ Burgess, L Malavolti, V Lanzilotto… - Nature …, 2015 - nature.com
Single-molecule magnets (SMMs) present a promising avenue to develop spintronic
technologies. Addressing individual molecules with electrical leads in SMM-based …

Pressure induced enhancement of the magnetic ordering temperature in rhenium (IV) monomers

CH Woodall, GA Craig, A Prescimone, M Misek… - Nature …, 2016 - nature.com
Materials that demonstrate long-range magnetic order are synonymous with information
storage and the electronics industry, with the phenomenon commonly associated with …

Pressure-tuning the quantum spin Hamiltonian of the triangular lattice antiferromagnet Cs2CuCl4

SA Zvyagin, D Graf, T Sakurai, S Kimura… - Nature …, 2019 - nature.com
Quantum triangular-lattice antiferromagnets are important prototype systems to investigate
numerous phenomena of the geometrical frustration in condensed matter. Apart from highly …

Bis (2, 1, 3-benzotelluradiazolidyl) 2, 1, 3-benzotelluradiazole: a pair of radical anions coupled by Te⋯ N chalcogen bonding

NA Puskarevsky, AI Smolentsev, AA Dmitriev… - Chemical …, 2020 - pubs.rsc.org
Reduction of 2, 1, 3-benzotelluradiazole (3) yielded a crystalline solid that features a trimeric
dianion formally composed of two [3]˙− and one 3 bridged by unusually asymmetric Te⋯ N …

Structural studies of perfluoroaryldiselenadiazolyl radicals: Insights into dithiadiazolyl chemistry

RL Melen, RJ Less, CM Pask, JM Rawson - Inorganic Chemistry, 2016 - ACS Publications
The synthesis and structural characterization of a series of perfluoroaryldiselenadiazolyls
[DSeDA; p-XC6F4CNSeSeN (X= F, Cl, Br, CF3, NO2, and CN for 2a–2f, respectively)] are …

Chalcogen exchange in chalcogen–nitrogen π-heterocycles

LS Konstantinova, OA Rakitin - Mendeleev Communications, 2021 - Elsevier
Chalcogen exchange in chalcogen–nitrogen π-heterocycles Page 1 Focus Article, Mendeleev
Commun., 2021, 31, 433–441 – 433 – Mendeleev Communications © 2021 Mendeleev …