Conspectus Oxidation reactions play a central role in organic synthesis, and it is highly
desirable that these reactions are mild and occur under catalytic conditions. In Nature …

Carbon monoxide, which is an abundant and inexpensive carbonyl source, has been widely
applied to synthesize carbonyl-containing compounds, for example ketones, esters, and …

Conspectus Palladium-catalyzed oxidations involving cascade processes provide a
versatile platform for streamlined conversion of simple feedstocks into functional molecules …

Herein, we report an electrochemical oxidative palladium‐catalyzed carbonylation‐
carbocyclization of enallenols to afford γ‐lactones and spirolactones, which proceeds with …

Presented herein is a mild, facile, and efficient iron‐catalyzed synthesis of substituted
allenes from propargyl carboxylates and Grignard reagents. Only 1–5 mol% of the …

A highly efficient dehydrogenative carbonylative esterification of allenoic acids using Pd-
catalysis was developed, providing a novel approach to synthesizing esterified γ …

A highly efficient palladium-catalyzed oxidative cascade reaction of enallenes undergoing
overall four C–C bond formations has been developed. The insertion cascade proceeds via …

A protocol for regio‐controlled hydromagnesiation of 1, 3‐enynes was developed using
magnesium hydride that is generated in situ by solvothermal treatment of sodium hydride …

Conspectus Organic synthesis based on straightforward transformations is essential for
environmentally benign manufacturing for the invention of novel pharmaceuticals …

A highly efficient palladium‐catalyzed oxidative borylation of enallenes was developed for
the selective formation of cyclobutene derivatives and fully‐substituted alkenylboron …