Recent advances in supramolecular fullerene chemistry

X Chang, Y Xu, M von Delius - Chemical Society Reviews, 2023 - pubs.rsc.org
Fullerene chemistry has come a long way since 1990, when the first bulk production of C60
was reported. In the past decade, progress in supramolecular chemistry has opened some …

Exploration of Nano‐Saturns: A Spectacular Sphere–Ring Supramolecular System

S Toyota, E Tsurumaki - Chemistry–A European Journal, 2019 - Wiley Online Library
Saturn‐like systems consisting of nanoscale rings and spheres are fascinating motifs in
supramolecular chemistry. Several ring molecules are known to include spherical molecules …

Stoichiometry validation of supramolecular complexes with a hydrocarbon cage host by van't Hoff analyses

TM Fukunaga, Y Onaka, T Kato, K Ikemoto… - Nature …, 2023 - nature.com
Defining chemical processes with equations is the first important step in characterizing
equilibria for the assembly of supramolecular complexes, and the stoichiometry of the …

Selective Extraction of C70 by a Tetragonal Prismatic Porphyrin Cage

Y Shi, K Cai, H Xiao, Z Liu, J Zhou, D Shen… - Journal of the …, 2018 - ACS Publications
Along with the advent of supramolecular chemistry, research on fullerene receptors based
on noncovalent bonding interactions has attracted a lot of attention. Here, we present the …

Nano‐Saturn: Experimental Evidence of Complex Formation of an Anthracene Cyclic Ring with C60

Y Yamamoto, E Tsurumaki… - Angewandte Chemie …, 2018 - Wiley Online Library
An anthracene cyclic hexamer was synthesized by the coupling reaction as a macrocyclic
hydrocarbon host. This disk‐shaped host included a C60 guest in 1: 1 ratio to form a Saturn …

Modulating the properties of buckybowls containing multiple heteroatoms

G Zhu, Y Song, Q Zhang, W Ding, X Chen… - Organic Chemistry …, 2021 - pubs.rsc.org
Embedding heteroatoms in buckybowls is an effective approach to alter their electronic
structures and physicochemical properties. However, buckybowls with heteroatoms situated …

Phenine design for nanocarbon molecules

K Ikemoto, TM Fukunaga, H Isobe - … of the Japan Academy, Series B, 2022 - jstage.jst.go.jp
With the name “phenine” given to 1, 3, 5-trisubstituted benzene for a fundamental trigonal
planar unit to weave nanometer-sized networks, a series of curved nanocarbon molecules …

Feeding a Molecular Squid: A Pliable Nanocarbon Receptor for Electron-Poor Aromatics

R Frydrych, T Lis, W Bury, J Cybińska… - Journal of the …, 2020 - ACS Publications
A hybrid nanocarbon receptor consisting of a calix [4] arene and a bent oligophenylene loop
(“molecular squid”), was obtained in an efficient, scalable synthesis. The system contains an …

Stereoisomerism and structures of rigid cylindrical cycloarylenes

Z Sun, T Matsuno, H Isobe - Bulletin of the Chemical Society of …, 2018 - academic.oup.com
Stereoisomerism is one of the most fundamental and indispensable notions in chemistry. We
have recently found that a novel form of stereoisomerism emerges in cycloarylenes, cyclic …

Geodesic phenine frameworks

K Ikemoto, H Isobe - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
The planar trigonal structure of 1, 3, 5-trisubstituted benzene, named phenine, has been
adopted as basic units of polygonal networks to shape nanometer-sized curved organic π …