Catalytic C–H amination has recently emerged as a unique tool for the synthesis of amines.
This tutorial review highlights the existing protocols catalyzed by metal complexes (rhodium …

Transition metal-catalyzed C–H amination at positions adjacent to double bonds and
carbonyl groups is discussed in this critical review. While the focus will center on the recent …

Recent developments in catalytic C–H amination are discussed in this feature article. The
careful design of reagents and catalysts now provides efficient conditions for exquisitely …

Catalytic C–H amination reactions enable direct functionalization of non-activated C (sp3)–H
bonds with high levels of regio-, chemo-and stereoselectivity. As a powerful tool to unlock …

The significant progress made in the area of transition metal-catalyzed nitrene transfer into C–
H or CC bonds mediated by iodine (III) oxidants has been translated into many elegant …

Reaction between a sulfur (VI) compound and an iodine (III) oxidant in the presence of a
catalytic quantity (≤ 3 mol%) of a rhodium (II) catalyst leads to the formation of a chiral …

Nitrene transfer reactions are powerful tools in synthetic organic chemistry. In recent years,
transition-metal catalyzed nitrene transfer reactions with carbamates as the nitrene …

An automated continuous flow system capable of producing protected deoxy‐sugar donors
from commercial material is described. Four 2, 6‐dideoxy and two 3‐amino‐2, 3, 6‐trideoxy …

The activation of C–H bonds has become a widely used method which allows for the direct
transformation of C–H bonds into synthetically more valuable C–C and C–X bonds in a …

The combined C− H activation/Cope rearrangement (CHCR) is an effective C− H
functionalization process that has been used for the asymmetric synthesis of natural …