Organoboron compounds have become one of the most versatile building blocks in organic
synthesis owing to their accessible and efficient conversion into many different functional …

Organoboron compounds are powerful reagents in synthetic chemistry. Carbonyl and
carboxyl compounds are widely accessible chemical feedstocks. The synthesis of …

While 1, 2-addition represents the most common mode of alkyne hydroboration, herein we
describe a new 1, 1-hydroboration mode. It is the first demonstration of gem-(H, B) addition …

Organofluorine compounds are widely used in pharmaceutical, agrochemical, and materials
sciences. The syntheses and applications of fluorinated organoborons facilitate the rapid …

Organoborons are extremely important for synthetic organic chemistry; they can serve as
advanced intermediates for a variety of transformations. Such a well-known transformation …

The metal-catalyzed (Z)-selective hydroboration of terminal alkynes is synthetically
challenging due to the usually (E)-selective nature of the hydroboration and the formation of …

β-Difluoroalkylborons, featuring functionally important CF2 moiety and synthetically valuable
boron group, have great synthetic potential while remaining synthetically challenging …

An efficient cobalt-catalyzed selective hydroboration of 1, 3-enynes with HBpin toward 1, 3-
dienylboronate esters is disclosed. With a commercially available catalytic system of Co …

A modular, stereoselective route to trisubstituted (Z)-alkenyl (MIDA) boronates is described,
consisting of the radical addition–fragmentation of dithiocarbonates to 2-(MIDA) boronyl-3 …

The synthesis of α-boryl halohydrins via difunctionalization of alkenyl MIDA boronates has
been reported. Intriguing stereoselectivity was found with different halogen sources, which …