Application of phase-field method in rechargeable batteries

Q Wang, G Zhang, Y Li, Z Hong, D Wang… - npj Computational …, 2020 - nature.com
Rechargeable batteries have a profound impact on our daily life so that it is urgent to capture
the physical and chemical fundamentals affecting the operation and lifetime. The phase-field …

Dendrites and pits: untangling the complex behavior of lithium metal anodes through operando video microscopy

KN Wood, E Kazyak, AF Chadwick, KH Chen… - ACS central …, 2016 - ACS Publications
Enabling ultra-high energy density rechargeable Li batteries would have widespread impact
on society. However the critical challenges of Li metal anodes (most notably cycle life and …

Formation of magnesium dendrites during electrodeposition

R Davidson, A Verma, D Santos, F Hao… - ACS Energy …, 2018 - ACS Publications
We demonstrate the growth of dendritic magnesium deposits with fractal morphologies
exhibiting shear moduli in excess of values for polymeric separators upon the galvanostatic …

Uneven stripping behavior, an unheeded killer of Mg anodes

X Liu, A Du, Z Guo, C Wang, X Zhou, J Zhao… - Advanced …, 2022 - Wiley Online Library
Uniform magnesium (Mg) plating/stripping under high areal capacity utilization is critical for
the practical application of Mg‐metal anodes in rechargeable Mg batteries. However, the …

[HTML][HTML] Reversible Mg-ion insertion in a metastable one-dimensional polymorph of V2O5

JL Andrews, A Mukherjee, HD Yoo, A Parija… - Chem, 2018 - cell.com
The Li-ion paradigm of battery technology is constrained by the monovalency of the Li ion. A
straightforward solution is to transition to multivalent-ion chemistries, where Mg 2+ is the …

Mapping mechanisms and growth regimes of magnesium electrodeposition at high current densities

R Davidson, A Verma, D Santos, F Hao… - Materials …, 2020 - pubs.rsc.org
The utilization of metallic anodes holds promise for unlocking high gravimetric and
volumetric energy densities and is pivotal to the adoption of 'beyond Li'battery chemistries …

Simulating microgalvanic corrosion in alloys using the PRISMS phase-field framework

V Goel, Y Lyu, S DeWitt, D Montiel, K Thornton - MRS Communications, 2022 - Springer
In this prospective paper, we first review the existing simulation tools to simulate
microgalvanic corrosion during free immersion. Then, we describe a recently developed …

Phase-field simulation of interface growth of magnesium metal anodes during electrodeposition

J Wang, Y Zhao, H Hou - Journal of Energy Storage, 2023 - Elsevier
Mg-metal has abundant reserves and extremely high-volume capacity, making it an
excellent choice as the negative electrode for low-cost, high-volume energy-density …

Degradation Mechanisms of Magnesium Metal Anodes in Electrolytes Based on (CF3SO2)2N at High Current Densities

HD Yoo, SD Han, IL Bolotin, GM Nolis, RD Bayliss… - Langmuir, 2017 - ACS Publications
The energy density of rechargeable batteries utilizing metals as anodes surpasses that of Li
ion batteries, which employ carbon instead. Among possible metals, magnesium represents …

Three-dimensional magnesiophilic scaffolds for reduced passivation toward high-rate Mg metal anodes in a noncorrosive electrolyte

B Wan, H Dou, X Zhao, J Wang, W Zhao… - … applied materials & …, 2020 - ACS Publications
Magnesium ion batteries are a promising alternative of the lithium counterpart; however, the
poorly ion-conductive passivation layer on Mg metal makes plating/stripping difficult. In …