Artificial molecular ratchets: Tools enabling endergonic processes
Non‐equilibrium chemical systems underpin multiple domains of contemporary interest,
including supramolecular chemistry, molecular machines, systems chemistry, prebiotic …
including supramolecular chemistry, molecular machines, systems chemistry, prebiotic …
Ratcheting synthesis
Synthetic chemistry has traditionally relied on reactions between reactants of high chemical
potential and transformations that proceed energetically downhill to either a global or local …
potential and transformations that proceed energetically downhill to either a global or local …
Selective hydrodeoxygenation of 5-hydroxymethylfurfural (HMF) to 2, 5-dimethylfuran (DMF) over carbon supported copper catalysts using isopropyl alcohol as a …
Abstract Selective hydrodeoxygenation (HDO) of 5-hydroxymethylfurfural to 2, 5-
dimethylfuran is of great importance. We reveal a simple pathway for green and efficient …
dimethylfuran is of great importance. We reveal a simple pathway for green and efficient …
Fabrication of Large-Area Metal-on-Carbon Catalytic Condensers for Programmable Catalysis
Catalytic condensers stabilize charge on either side of a high-k dielectric film to modulate
the electronic states of a catalytic layer for the electronic control of surface reactions. Here …
the electronic states of a catalytic layer for the electronic control of surface reactions. Here …
Flexible and Extensive Platinum Ion Gel Condensers for Programmable Catalysis
Catalytic condensers composed of ion gels separating a metal electrode from a platinum-on-
carbon active layer were fabricated and characterized to achieve more powerful, high …
carbon active layer were fabricated and characterized to achieve more powerful, high …
Molecular ratchets and kinetic asymmetry: Giving chemistry direction
Over the last two decades ratchet mechanisms have transformed the understanding and
design of stochastic molecular systems—biological, chemical and physical—in a move away …
design of stochastic molecular systems—biological, chemical and physical—in a move away …
Dynamic Electrification of Dry Reforming of Methane with In Situ Catalyst Regeneration
We report the design and performance of a rapid pulse Joule heating (RPH) reactor with an
in situ Raman spectrometer for highly endothermic, reversible reactions. We demonstrate it …
in situ Raman spectrometer for highly endothermic, reversible reactions. We demonstrate it …
Deep learning-assisted investigation of electric field–dipole effects on catalytic ammonia synthesis
External electric fields can modify binding energies of reactive surface species and enhance
catalytic performance of heterogeneously catalyzed reactions. In this work, we used density …
catalytic performance of heterogeneously catalyzed reactions. In this work, we used density …
Platinum graphene catalytic condenser for millisecond programmable metal surfaces
TM Onn, SR Gathmann, S Guo… - Journal of the …, 2022 - ACS Publications
Accelerating catalytic chemistry and tuning surface reactions require precise control of the
electron density of metal atoms. In this work, nanoclusters of platinum were supported on a …
electron density of metal atoms. In this work, nanoclusters of platinum were supported on a …
Reaction mechanisms, kinetics, and improved catalysts for ammonia synthesis from hierarchical high throughput catalyst design
J Fuller, Q An, A Fortunelli… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus The Haber–Bosch (HB) process is the primary chemical synthesis technique for
industrial production of ammonia (NH3) for manufacturing nitrate-based fertilizer and as a …
industrial production of ammonia (NH3) for manufacturing nitrate-based fertilizer and as a …