Coinage metal hydrides: synthesis, characterization, and reactivity

AJ Jordan, G Lalic, JP Sadighi - Chemical Reviews, 2016 - ACS Publications
Hydride complexes of copper, silver, and gold encompass a broad array of structures, and
their distinctive reactivity has enabled dramatic recent advances in synthesis and catalysis …

Equation-of-Motion Methods for the Calculation of Femtosecond Time-Resolved 4-Wave-Mixing and N-Wave-Mixing Signals

MF Gelin, L Chen, W Domcke - Chemical Reviews, 2022 - ACS Publications
Femtosecond nonlinear spectroscopy is the main tool for the time-resolved detection of
photophysical and photochemical processes. Since most systems of chemical interest are …

Quantum chemical calculation of electron ionization mass spectra for general organic and inorganic molecules

V Ásgeirsson, CA Bauer, S Grimme - Chemical Science, 2017 - pubs.rsc.org
We introduce a fully stand-alone version of the Quantum Chemistry Electron Ionization Mass
Spectra (QCEIMS) program [S. Grimme, Angew. Chem. Int. Ed., 2013, 52, 6306] allowing …

Poly‐Hydride [AuI7(PPh3)7H5](SbF6)2 cluster complex: Structure, Transformation, and Electrocatalytic CO2 Reduction Properties

L Tang, Y Luo, X Ma, B Wang, M Ding… - Angewandte Chemie …, 2023 - Wiley Online Library
Hydride AuI bonds are labile due to the mismatch in electric potential of an oxidizing metal
and reducing ligand, and therefore the structure and structure–activity relationships of …

Interconnection between Polarization-Detected and Population-Detected Signals: Theoretical Results and Ab Initio Simulations

K Sun, L Vasquez, R Borrelli, L Chen… - Journal of Chemical …, 2024 - ACS Publications
Most of spectroscopic signals are specified by the nonlinear laser-induced polarization. In
recent years, population-detection of signals becomes a trend in femtosecond spectroscopy …

Catalytic CO oxidation by gas-phase metal oxide clusters

XN Li, LN Wang, LH Mou, SG He - The Journal of Physical …, 2019 - ACS Publications
Oxidation of CO into CO2 is a prototypical reaction in heterogeneous catalysis and is one of
the extensively studied reactions in the gas phase to explore the underlying mechanisms of …

Size-Dependent Reactivity of Con (n = 5–25) Cluster Anions toward Carbon Dioxide

XY He, YZ Liu, JJ Chen, X Lan, XN Li… - The Journal of Physical …, 2023 - ACS Publications
A fundamental understanding of the reactivity evolution of nanosized clusters at an
atomically precise level is pivotal to assemble desired materials with promising candidates …

Electronic spectroscopy of homo-and heterometallic binuclear coinage metal phosphine complexes in isolation

MJP Schmitt, SV Kruppa, SP Walg, WR Thiel… - Physical Chemistry …, 2023 - pubs.rsc.org
Binuclear coinage metal phosphine complexes are examined under ion trap isolation in
order to elucidate their noncovalent binding, structural properties and intrinsic electronic …

Formation of Gas‐Phase Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions

LX Jiang, C Zhao, XN Li, H Chen… - Angewandte Chemie …, 2017 - Wiley Online Library
The hydrogenation of carbon dioxide involves the activation of the thermodynamically very
stable molecule CO2 and formation of a C− H bond. Herein, we report that HCO2− and CO …

Neutral Au1-Doped Cluster Catalysts AuTi2O3–6 for CO Oxidation by O2

JJ Chen, XN Li, Q Chen, QY Liu… - Journal of the …, 2018 - ACS Publications
Oxide supported gold catalysts (eg, Au/TiO2) are of great significance in heterogeneous
catalysis owing to their extraordinary catalytic activity. Study of heteronuclear metal oxide …