When “dark” is bright: the scarcely explored electrophilic profile of the indolyl core (dark‐
side) continues to inspire developments in organic synthesis by means of new catalytic …

We report the use of electrochemistry to perform a direct oxidative dearomatization of
indoles leading to 2, 3-dialkoxy or 2, 3-diazido indolines under undivided conditions at a …

The dearomative introduction of trifluoromethyl and 1, 1-difluoroethyl radicals, generated
from their corresponding sulfinate salts, into the C2 position of indole derivatives allows the …

This Account summarizes our involvement in the development of dearomatization reactions
of indoles that has for origin a total synthesis problematic. We present the effort from our …

In this study, we try to develop an effective route to the preparation of hollow mesoporous
boron nitride spheres (HMBNS) with surface decorated by CuO for the synthesis of some …

Three-dimensional indolines possessing two contiguous-stereogenic centers were obtained
stereoselectively via the FeCl3-mediated dearomative introduction of two allyl groups to N …

Electrophilic indoles bearing a leaving group at C2 undergo C3-regioselective dearomative
hydroaryloxylation and subsequent 1, 2-tertiary alkyl migration/aromatization. This is the first …

The present feature article details our endeavors towards the synthesis of the highly intricate
bisindole alkaloid bipleiophylline and its biosynthetic precursor voacalgine A: from the …

Subsequent reduction and dearomatizing cyclization reactions open up an entry into the
synthesis of novel N‐fused polycyclic indolines. The dearomatizing cyclization as key step of …

A catalytic approach for the preparation of indolines by dearomatizing cyclization is
presented. FeCl3 acts as a catalyst to afford tetracyclic 5a, 6-dihydro-12 H-indolo [2, 1-b][1 …