Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Nanoconfinement and mass transport in metal–organic frameworks

CH Sharp, BC Bukowski, H Li, EM Johnson… - Chemical Society …, 2021 - pubs.rsc.org
The ubiquity of metal–organic frameworks in recent scientific literature underscores their
highly versatile nature. MOFs have been developed for use in a wide array of applications …

Effective toluene adsorption over defective UiO-66-NH2: an experimental and computational exploration

X Shi, X Zhang, F Bi, Z Zheng, L Sheng, J Xu… - Journal of Molecular …, 2020 - Elsevier
In this thesis, defective UiO-66-NH 2 using cetyltrimethylammonium bromide (CTAB) as a
template was successfully synthesized. The toluene adsorption-desorption properties were …

Evolution of acid and basic sites in UiO-66 and UiO-66-NH2 metal-organic frameworks: FTIR study by probe molecules

K Chakarova, I Strauss, M Mihaylov, N Drenchev… - Microporous and …, 2019 - Elsevier
Metal-organic frameworks (MOFs) and MOF-based materials find increasing and diverse
applicability. The performance of MOFs in adsorption and catalysis is strongly related to their …

MOFs in the time domain

DJ Cerasale, DC Ward, TL Easun - Nature Reviews Chemistry, 2022 - nature.com
Many of the proposed applications of metal–organic framework (MOF) materials may fail to
materialize if the community does not fully address the difficult fundamental work needed to …

What factors determine activity of UiO-66 in H2O2-based oxidation of thioethers? The role of basic sites

VY Evtushok, KP Larionov, VA Lopatkin, OA Stonkus… - Journal of …, 2023 - Elsevier
Zr-based metal–organic frameworks (Zr-MOFs) have attracted significant attention as
selective oxidation catalysts due to their stability in aqueous and oxidative media and high …

Paired Electrochemical N–N Coupling Employing a Surface-Hydroxylated Ni3Fe-MOF-OH Bifunctional Electrocatalyst with Enhanced Adsorption of Nitroarenes and …

W Qiao, I Waseem, G Shang, D Wang, Y Li… - ACS …, 2021 - ACS Publications
Paired electrolysis employing both anodic and cathodic half reactions for the synthesis of
value-added chemicals is an ultimate energy-efficient approach. Here, we show that paired …

Anomalous infrared intensity behavior of acetonitrile diffused into UiO-67

RP McDonnell, VSD Devulapalli, TH Choi… - Chemistry of …, 2023 - ACS Publications
UiO-67 metal–organic frameworks (MOFs) show promise for use in a variety of areas,
especially in industrial chemistry, as stable and customizable catalyst materials often driven …

Metal–organic framework-and polyoxometalate-based sorbents for the uptake and destruction of chemical warfare agents

TG Grissom, AM Plonka, CH Sharp… - … applied materials & …, 2020 - ACS Publications
The threat of chemical warfare agents (CWAs), assured by their ease of synthesis and
effectiveness as a terrorizing weapon, will persist long after the once-tremendous stockpiles …

Benzene, toluene, and xylene transport through UiO-66: diffusion rates, energetics, and the role of hydrogen bonding

TG Grissom, CH Sharp, PM Usov, D Troya… - The Journal of …, 2018 - ACS Publications
The high-energy demand of benzene, toluene, and xylene (BTX) separation highlights the
need for improved nonthermal separation techniques and materials. Because of their high …