Elaborated molecular architectures, especially carbocyclic, heterocyclic, endocyclic, and
polycyclic molecular structures, serve as an important class of organic complexes because …

The hydridic hydrogen in nanogold catalysts has long been postulated as an important
intermediate in hydrogenation reactions, but it has not been directly observed. Here, we …

Gold catalysis has emerged as an important tool in the field of synthetic organic chemistry for
the selective functionalization of C–C multiple bonds. The research in India on gold catalysis …

Classically tetraaryl diphosphanes have been synthesized through Wurtz-type reductive
coupling of halophosphanes R2PX or more recently, through the dehydrocoupling of …

A novel class of (P^ N^ C) pincer ligands capable of stabilizing elusive gold (III) species is
reported here. Straightforward access to (P^ N^ C) gold (III) hydroxo, formate, and hydride …

A cavity-shaped linear gold (I) hydroxide complex acts as a platform to access unusual gold
monomeric species. Notably, this sterically crowded gold fragment enables the trapping of …

We analyzed the ligand electronic effect in the reaction between a [LAu (I) H] 0/− hydride
species and CO2, leading to a coordinated formate [LAu (HCOO)] 0/−. We explored 20 …

A diphosphene ligand possessing a PP bond and a phosphineborane moiety in its molecule
was synthesized. The reaction of the new bidentate diphosphene–phosphineborane ligand …

The role of the coinage metal in monomeric hydride complexes for the reduction of carbon
dioxide to formate has been computationally addressed in this work. The common reaction …

Organophosphorus compounds possessing a P–P double-bond character are intriguing
materials in coordination chemistry because it is possible to form a variety of coordination …