Abstract The stereospecific 1, 2‐migration of boronate complexes is one of the most
representative reactions in boron chemistry. This process has been used extensively to …

The in-depth research on merging organoboron reagents with unique characteristics and
asymmetric tandem reaction strategy has inspired particular interest on account of the …

Abstract In recent years, numerous 1, 2-R shift (R= aliphatic or aryl) based on
tetracoordinate boron species have been well investigated. In the contrary, the …

Asymmetric cross‐couplings based on 1, 2‐carbon migration from B‐ate complexes have
been developed efficiently to access valuable organoboronates. However, enantioselective …

Enantio-and diastereoselective conjunctive cross-coupling of β-substituted alkenylboron
“ate” complexes is studied. Whereas β-substitution shifts the chemoselectivity of the catalytic …

An unprecedented visible-light-induced transition-metal-free alkynylation of alkyl pinacol
boronates has been demonstrated with alkynyl phenylsulfones as the alkynylation reagents …

The amino group is one of the most fundamental structural motifs in natural products and
synthetic chemicals. However, amines potential as effective alkylating agents in organic …

A base‐catalyzed reaction that enables stereoselective 1, 1‐silaboration of terminal alkynes
is described. This method not only offers a new strategy to functionalize simple and readily …

Furan‐and indole‐derived boronate complexes react with alkyl iodides under radical
(photoredox) or polar (SN2) conditions to generate three‐component alkylation products …

The coupling of ortho‐and para‐phenols with secondary and tertiary boronic esters has
been explored. In the case of para‐substituted phenols, after reaction of a dilithio phenolate …