Metal‐Catalyzed Hydrophosphination
BT Novas, R Waterman - ChemCatChem, 2022 - Wiley Online Library
Organophosphines have garnered attention from many avenues ranging from agriculture to
fine chemicals. One‐time use of phosphate resources has made sustainable use of …
fine chemicals. One‐time use of phosphate resources has made sustainable use of …
Broken promises? On the continued challenges faced in catalytic hydrophosphination
S Lau, TM Hood, RL Webster - ACS catalysis, 2022 - ACS Publications
In this Perspective, we discuss what we perceive to be the continued challenges faced in
catalytic hydrophosphination chemistry. Currently the literature is dominated by catalysts …
catalytic hydrophosphination chemistry. Currently the literature is dominated by catalysts …
Use of organolanthanides in the catalytic intermolecular hydrophosphination and hydroamination of multiple C–C bonds
AA Trifonov, IV Basalov, AA Kissel - Dalton Transactions, 2016 - pubs.rsc.org
Use of organolanthanides in the catalytic intermolecular hydrophosphination and
hydroamination of multiple C–C bonds - Dalton Transactions (RSC Publishing) DOI:10.1039/C6DT03913H …
hydroamination of multiple C–C bonds - Dalton Transactions (RSC Publishing) DOI:10.1039/C6DT03913H …
Thermally Stable Ln (II) and Ca (II) Bis (benzhydryl) Complexes: Excellent Precatalysts for Intermolecular Hydrophosphination of C–C Multiple Bonds
AN Selikhov, GS Plankin, AV Cherkasov… - Inorganic …, 2019 - ACS Publications
A series of Ln (II) and Ca (II) bis (alkyl) complexes with bulky benzhydryl ligands,[(pt Bu-
C6H4) 2CH] 2M (L n)(M= Sm, L= DME, n= 2 (1); M= Sm, Yb, Ca, L= TMEDA, n= 1 (2, 3, 4) …
C6H4) 2CH] 2M (L n)(M= Sm, L= DME, n= 2 (1); M= Sm, Yb, Ca, L= TMEDA, n= 1 (2, 3, 4) …
Calcium hydride insertion reactions with unsaturated C–C bonds
The dimeric β-diketiminato calcium hydride,[(BDI) CaH] 2 (BDI= HC {(Me) CN-2, 6-i-
Pr2C6H3} 2), reacts with terminal alkenes to provide the corresponding alkyl derivatives …
Pr2C6H3} 2), reacts with terminal alkenes to provide the corresponding alkyl derivatives …
CaII, YbII and SmII Bis(Amido) Complexes Coordinated by NHC Ligands: Efficient Catalysts for Highly Regio‐ and Chemoselective Consecutive Hydrophosphinations with PH …
IV Lapshin, IV Basalov, KA Lyssenko… - … A European Journal, 2019 - Wiley Online Library
The first example of intermolecular hydrophosphination of styrene, 2‐vinylpyridine and
phenylacetylene with PH3 catalyzed by bis‐(amido) complexes [(Me3Si) 2N] 2M (NHC) 2 …
phenylacetylene with PH3 catalyzed by bis‐(amido) complexes [(Me3Si) 2N] 2M (NHC) 2 …
Ln (ii) amido complexes coordinated by ring-expanded N-heterocyclic carbenes–promising catalysts for olefin hydrophosphination
IV Lapshin, AV Cherkasov, AF Asachenko… - Chemical …, 2020 - pubs.rsc.org
Ln( ii ) amido complexes coordinated by ring-expanded N-heterocyclic carbenes – promising
catalysts for olefin hydrophosphination - Chemical Communications (RSC Publishing) …
catalysts for olefin hydrophosphination - Chemical Communications (RSC Publishing) …
Mechanism and Catalyst Design in Ru-Catalyzed Alkene Hydrophosphination
A thorough experimental examination of a series of half-sandwich Ru indenyl complexes
[Ru (η5-indenyl)(PPh2)(L)(PPh3)(L= PPh2H, CO, NCPh)] in the catalytic …
[Ru (η5-indenyl)(PPh2)(L)(PPh3)(L= PPh2H, CO, NCPh)] in the catalytic …
Alkyl complexes of divalent lanthanides and heavy alkaline earth metals
DO Khristolyubov, DM Lyubov… - Russian Chemical …, 2021 - iopscience.iop.org
The review presents data on the synthesis, structure, reactivity, and catalytic activity of alkyl
derivatives of rare earth metals in the oxidation state+ 2 (Sm, Eu, Yb) and their analogues …
derivatives of rare earth metals in the oxidation state+ 2 (Sm, Eu, Yb) and their analogues …
N-Heterocyclic Carbene-Coordinated M(II) (M = Yb, Sm, Ca) Bisamides: Expanding the Limits of Intermolecular Alkene Hydrophosphination
IV Lapshin, AV Cherkasov, KA Lyssenko… - Inorganic …, 2022 - ACS Publications
A series of NHC-stabilized amido compounds (NHC) n M [N (SiMe3) 2] 2 (M= Yb (II), Sm (II),
Ca (II); n= 1, 2) showed remarkable catalytic efficiency in addition of PhPH2 and PH3 to …
Ca (II); n= 1, 2) showed remarkable catalytic efficiency in addition of PhPH2 and PH3 to …