Useful designs in the synthesis of trans-fused polyether toxins

E Alvarez, ML Candenas, R Perez, JL Ravelo… - Chemical …, 1995 - ACS Publications
/. Introduction and Genera! Remarks Marine dinoflagellates are attracting more and more
attention as a source of compounds with unique structures and useful biological activity. 1 …

[图书][B] Asymmetric synthetic methodology

DJ Ager, MB East - 2020 - taylorfrancis.com
This comprehensive text presents a critical discussion of the scopes and limitations of
various organic synthetic methodologies that are available for performing asymmetric …

Recent developments in the synthesis of medium ring ethers

CJ Moody, MJ Davies - Studies in Natural Products Chemistry …, 2013 - books.google.com
Natural products containing a medium ring ether are widespread, and show a fascinating
spectrum of structure and biological activity. The halogenated enyne laurencin (1) and the …

A centennial methodology for the preparation of heterocyclic compounds: The intramolecular coiodination of alkenes with internal oxygenated nucleophiles

FM da Silva, JJ Junior… - Current Organic Synthesis, 2005 - ingentaconnect.com
A review on the intramolecular coiodination of alkenes with internal oxygenated
nucleophiles (alkenols, unsaturated ethers, carboxylic acids and derivatives) is presented …

Model studies directed towards microalga polyether toxins. A stereoselective entry into C8 oxepane subunits

E Alvarez, MT Díaz, R Pérez, JD Martín - Tetrahedron letters, 1991 - Elsevier
A new synthetic strategy for the regio and stereospecific synthesis of meso β-alkoxy-
substituted oxepanes involving iodine promoted transannular ring expansion of 9 …

Conversion of alkyl halides into alcohols via formyloxylation reaction with DMF catalyzed by silver salts

A Abad, C Agullo, AC Cunat, I Navarro - Synthesis, 2005 - thieme-connect.com
The transformation of alkyl halides into alcohols via a two-step process based on the
reaction with DMF catalyzed by Ag (I) salts followed by acid or basic hydrolysis of the …

In situ nitrosonium ion generation — α-Oximinylation of enol ethers from steroidal spiroketals: Introduction of C23 (R)-OH in cephalostatin intermediates

S Lee, PL Fuchs - Canadian journal of chemistry, 2006 - cdnsciencepub.com
L'ion nitrosonium généré in situ par réaction du t-BuNO2 avec le BF3⊙ OEt2 est un agent
d'oximinylation efficace pour les éthers énoliques dérivés de spirocétals stéroïdaux. On a …

Synthesis of the 10-oxabicyclo [5.2. 1] decane framework present in bioactive natural products

ÁM Montaña, S Ponzano, MF Sanasi… - Organic & Biomolecular …, 2018 - pubs.rsc.org
The present work deals with the synthesis of the 10-oxabicyclo [5.2. 1] decane framework
present in bioactive natural products like physalins, with potential as antitumor agents. This …

Versatile Methodology to Synthesize Oxygen‐Bridged Nine‐and Ten‐Membered Cycloalkanes by the Hypoiodite Reaction

ÁM Montaña, S Ponzano, G Kociok‐Köhn… - 2007 - Wiley Online Library
Abstract C‐3 derivatives of 6‐hydroxy‐2, 7‐dimethyl‐11‐oxatricyclo [6.2. 1.02, 6] undecan‐4‐
one reacted with lead tetraacetate (LTA) and iodine to afford, in good yield, 1, 7 …

Recent advances in stereochemistry reveal classification shortcomings

PJ Canfield, LJ Govenlock, J Reimers, MJ Crossley - 2020 - chemrxiv.org
We contend that the Polytope model utilized by IUPAC to specify stereoisomerism for
species MLn with n> 3 should be universally applied. Such application recently led to the …