1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) is a polar, strongly hydrogen bond-donating
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …

Second-and third-row transition metal complexes are widely employed in photocatalysis,
whereas earth-abundant first-row transition metals have found only limited use because of …

Covalent organic frameworks (COFs) have received broad interest owing to their permanent
porosity, high stability, and tunable functionalities. COFs with long‐range π‐conjugation and …

Organoboron compounds are well known building blocks for many organic reactions.
However, under basic conditions, polyfluorinated aryl boronic acid derivatives suffer from …

Combining more than two metal–organic frameworks (MOFs) with different structures is an
intelligent strategy for the architecture of hybrid MOFs. Herein, well-organized UiO-66 (Zr)-on …

Functionalization of arenes is a topic of central importance in diverse fields ranging from
medicinal chemistry to materials science. Metal-catalyzed cross-coupling and nucleophilic …

Herein, we report the rational design of a modular dual photoredox and cobalt catalysis
paradigm for the difunctionalization of unsaturated hydrocarbons, unlocking the synthesis of …

Nitroaromatic compounds represent one of the essential classes of molecules that are
widely used as feedstock for the synthesis of intermediates, the preparation of nitro‐derived …

We report a site-selective ipso-nitration of aryl germanes in the presence of boronic esters,
silanes, halogens, and additional functionalities. The protocol is characterized by …

Nitro compounds are vital raw chemicals that are widely used in academic laboratories and
industries for the preparation of various drugs, agrochemicals, and materials. Thus, nitrating …