Within the sphere of traditional Pd0/PdII cross coupling reactions, organogermanes have
been historically outperformed both in terms of scope and reactivity by more conventional …

Abstract Comprehensive Summary: Hydrogermylation of alkenes and alkynes provides a
straightforward synthetic route to organogermanium compounds that have been found …

Cross‐electrophile coupling has emerged as a promising tool for molecular synthesis;
however, current studies have focused mainly on forging C− C bonds. We report a cross …

A copper-catalyzed asymmetric synthesis of unnatural β-germyl α-amino acids is developed.
This process undergoes an intermolecular enantioselective hydrogermylation of …

A simple and efficient strategy for iron-catalysed cascade radical cyclization was developed,
by which an array of germanium-substituted indolo [2, 1-a] isoquinolin-6 (5H)-ones and …

The concurrent incorporation of a germyl fragment and another functional group (beyond the
hydrogen atom) across the C═ C double bond is a highly appealing yet challenging task …

This Letter discloses the straightforward hydrogermylation of olefins under visible-light
organophotoredox-initiated HAT catalysis conditions to yield primary and secondary alkyl …

The functionalization of alkynylgermanes using hydrosilanes was accomplished by
employing cobalt catalysis. Depending on the reactants used, the reaction can proceed via …

While migratory functionalization of alkynes has been recognized as a unique way to access
allylic functionalities via π-allyl metal intermediates, hydrofunctionalization of 2-alkynes to …

The incorporation of a germyl group and another functional fragment across the C═ C bond
is a challenging task due to the prevailing hydrogermylation reaction. Herein, an efficient …