Supramolecular chiroptical switches

L Zhang, HX Wang, S Li, M Liu - Chemical Society Reviews, 2020 - pubs.rsc.org
Chiroptical switches, whose chiral optical signals such as optical rotatory dispersion (ORD),
circular dichroism (CD) and circularly polarized luminescence (CPL) are reversibly …

Enantioenriched helicenes and helicenoids containing main-group elements (B, Si, N, P)

K Dhbaibi, L Favereau, J Crassous - Chemical reviews, 2019 - ACS Publications
In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-
group elements. Enantioenriched helicenic derivatives containing main-group elements B …

Circularly polarized luminescence and circular dichroisms in small organic molecules: correlation between excitation and emission dissymmetry factors

H Tanaka, Y Inoue, T Mori - ChemPhotoChem, 2018 - Wiley Online Library
Prompted by the recent rapid growth of interest in circularly polarized luminescence (CPL) of
organic molecules, we have collected all the reliable CPL, as well as the corresponding …

Combined reversible switching of ECD and quenching of CPL with chiral fluorescent macrocycles

A Homberg, E Brun, F Zinna, S Pascal, M Górecki… - Chemical …, 2018 - pubs.rsc.org
Straightforward synthesis and resolution of a series of chiral fluorescent macrocycles are
presented, together with their electronic circular dichroism (ECD), strong excimer …

Emergent properties of an organic semiconductor driven by its molecular chirality

Y Yang, B Rice, X Shi, JR Brandt, R Correa da Costa… - ACS …, 2017 - ACS Publications
Chiral molecules exist as pairs of nonsuperimposable mirror images; a fundamental
symmetry property vastly underexplored in organic electronic devices. Here, we show that …

Natural-based chiral task-specific deep eutectic solvents: A novel, effective tool for enantiodiscrimination in electroanalysis

S Arnaboldi, A Mezzetta, S Grecchi, M Longhi… - Electrochimica …, 2021 - Elsevier
Abstract Deep Eutectic Solvents (DESs) offer advantages similar to ionic liquid (IL) ones,
with easier and more sustainable synthesis; moreover, bio-based DESs often include chiral …

Mix and Match Tuning of the Conformational and Multistate Redox Switching Properties of an Overcrowded Alkene

R Hein, CN Stindt, BL Feringa - Journal of the American Chemical …, 2024 - ACS Publications
Overcrowded alkenes have received considerable attention as versatile structural motifs in a
range of optical switches and light-driven unidirectional motors. In contrast, their actuation by …

Synthesis of Closed‐Heterohelicenes Interconvertible between Their Monomeric and Dimeric Forms

Y Matsuo, C Maeda, Y Tsutsui, T Tanaka… - Angewandte …, 2023 - Wiley Online Library
Oxidative fusion reaction of cyclic heteroaromatic pentads consisting of pyrrole and
thiophene gave closed‐heterohelicene monomers and dimers depending on the oxidation …

Pd-Catalyzed Dual C–H Activation/Cyclization: Convergent and Divergent Synthesis of 1-Azahelicenes

YX Xu, YQ Liang, WM Liu, HK Fang, HK Li, SJ Ji… - Organic …, 2024 - ACS Publications
Herein, we report a convergent synthesis of 1-azahelicenes using easily available quinoline
derivatives and cyclic diaryliodonium salts as starting materials. This reaction undergoes a …

Keto–enol equilibrium: stable tautomers of ortho-, meta-, and para-hydroquinones in large aromatics

V Silber, C Gourlaouen, R Ruppert - RSC advances, 2024 - pubs.rsc.org
The synthesis of [6] helicene para-quinone starting from the 1, 4-dimethoxy-[6] helicene
derivative is presented. The demethylation reaction with boron tribromide led to unexpected …