Exploring the topological landscape exhibited by binary zinc-triad 1, 1-dithiolates

ERT Tiekink - Crystals, 2018 - mdpi.com
The crystal chemistry of the zinc-triad binary 1, 1-dithiolates, that is, compounds of xanthate
[− S2COR], dithiophosphate [− S2P (OR) 2], and dithiocarbamate [− S2CNR2] ligands, is …

Perplexing coordination behaviour of potentially bridging bipyridyl-type ligands in the coordination chemistry of zinc and cadmium 1, 1-dithiolate compounds

ERT Tiekink - Crystals, 2018 - mdpi.com
The X-ray structural chemistry of zinc and cadmium 1, 1-dithiolates (for example, xanthate,
dithiophosphate and dithiocarbamate) with potentially bridging bipyridyl-type ligands (for …

A Computational Chemistry Investigation of the Influence of Steric Bulk of Dithiocarbamato-Bound Organic Substituents upon Spodium Bonding in Three Homoleptic …

RM Gomila, ERT Tiekink, A Frontera - Inorganics, 2023 - mdpi.com
Three homoleptic Hg (S2CNR2) 2, for R= ethyl (1), isobutyl (2), and cyclohexyl (3),
compounds apparently exhibit a steric-dependent supramolecular association in their …

Effect of solvent used for crystallization on structure: Synthesis and characterization of bis (N, N-di (4-fluorobenzyl) dithiocarbamato-S, S′) M (II)(M= Cd, Hg) and …

S Eswari, P Selvaganapathi, S Thirumaran, S Ciattini - Polyhedron, 2021 - Elsevier
Abstract Bis (N, N-di (4-fluorobenzyl) dithiocarbamato-S, S′) M (II).(M= Cd (1), Hg (2)) were
prepared and fully characterized. Recrystallization of 1 from its chloroform-acetonitrile and …

Effect of functionalities on the crystal structures of new zinc (II) dithiocarbamates: A combined anti-leishmanial and thermal decomposition study

KK Manar, CL Yadav, N Tiwari, RK Singh, A Kumar… - …, 2017 - pubs.rsc.org
New homoleptic zinc (II) dithiocarbamates,[Zn (L) 2](L= N-ferrocenyl-N-methyl
dithiocarbamate (L1) 1,(N-(benzo [d][1, 3] dioxol-5-ylmethyl)-N-furfuryl) dithiocarbamate (L2) …

Snap frozen! capturing two metastable polymorphs in a tetramorphic one-dimensional coordination polymer constructed from cadmium, dithiophosphate, and 4 …

YS Tan, A Otero-de-la-Roza, MM Jotani… - Crystal Growth & …, 2020 - ACS Publications
Four polymorphs are described for the one-dimensional coordination polymer {Cd [S2P
(OMe) 2] 2 (4-pyridine-aldazine)} n (1) which features a trans-N2S4 distorted octahedral …

A new structural motif for cadmium dithiocarbamates: crystal structures and Hirshfeld surface analyses of homoleptic zinc and cadmium morpholine dithiocarbamates

J Ahmad, FNF How, SNA Halim, MM Jotani… - Zeitschrift für …, 2019 - degruyter.com
The crystal and molecular structures of two homoleptic morpholine-derived
dithiocarbamates of zinc, binuclear {Zn [S2CN (CH2CH2) 2O) 2] 2} 2 (1), and cadmium, one …

Hydroxyl group interactions in metal dithiocarbamate complexes containing 2-hydroxyethyl substituents. Crystal structure determination, theoretical and Hirshfeld …

GM de Lima, CHS Lima, SP Machado… - Journal of Molecular …, 2022 - Elsevier
X-ray crystal structure, theoretical and Hirshfeld surface study of tris (2-hydroxyethyl (ethyl)
aminodi-thiocarbamato) indium (III) is reported. The arrangement of the sulfur atoms around …

[PDF][PDF] [μ2-trans-1, 2-Bis (pyridin-4-yl) ethene-κ2N: N′] bis {[1, 2-bis (pyridin-4-yl) ethene-κN] bis [N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S, S′] cadmium} …

MM Jotani, P Poplaukhin, HD Arman… - Acta Crystallographica …, 2016 - journals.iucr.org
The asymmetric unit of the title compound,[Cd2 (C12H10N2) 3 (C6H12NOS2) 4]· 4C2H3N,
comprises a CdII atom, two dithiocarbamate (dtc) anions, one and a half trans-1, 2-dipyridin …

[PDF][PDF] Bis [N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S, S′](piperazine-κN) cadmium: crystal structure and Hirshfeld surface analysis

SAM Safbri, SNA Halim, MM Jotani… - Acta Crystallographica …, 2016 - journals.iucr.org
The title compound,[Cd (C6H12NOS2) 2 (C4H10N2)], features a distorted square-pyramidal
coordination geometry about the central CdII atom. The dithiocarbamate ligands are …