A guide to secondary coordination sphere editing
MW Drover - Chemical Society Reviews, 2022 - pubs.rsc.org
This tutorial review showcases recent (2015–2021) work describing ligand construction as it
relates to the design of secondary coordination spheres (SCSs). Metalloenzymes, for …
relates to the design of secondary coordination spheres (SCSs). Metalloenzymes, for …
Synthetic Fe/Cu complexes: toward understanding heme-copper oxidase structure and function
Heme-copper oxidases (HCOs) are terminal enzymes on the mitochondrial or bacterial
respiratory electron transport chain, which utilize a unique heterobinuclear active site to …
respiratory electron transport chain, which utilize a unique heterobinuclear active site to …
Tunable σ-accepting, Z-type ligands for organometallic catalysis
Over the past decade, the chemistry of σ-accepting or Z-type ligands based on main group
elements has drawn renewed attention because of the realization that their interaction with a …
elements has drawn renewed attention because of the realization that their interaction with a …
Intramolecular hydrogen bonding enhances stability and reactivity of mononuclear cupric superoxide complexes
[(L) CuII (O2•–)]+(ie, cupric-superoxo) complexes, as the first and/or key reactive
intermediates in (bio) chemical Cu-oxidative processes, including in the monooxygenases …
intermediates in (bio) chemical Cu-oxidative processes, including in the monooxygenases …
Iron-Catalyzed C–H Oxygenation Using Perchlorate Enabled by Secondary Sphere Hydrogen Bonds
Perchlorate (ClO4–) is a groundwater pollutant that is challenging to remediate. We report a
strategy to use Fe (II) tris (2-pyridylmethyl) amine (TPA) complexes featuring appended …
strategy to use Fe (II) tris (2-pyridylmethyl) amine (TPA) complexes featuring appended …
What Is the Right Level of Activation of a High-Spin {FeNO}7 Complex to Enable Direct N–N Coupling? Mechanistic Insight into Flavodiiron NO Reductases
Flavodiiron nitric oxide reductases (FNORs), found in pathogenic bacteria, are capable of
reducing nitric oxide (NO) to nitrous oxide (N2O) to detoxify NO released by the human …
reducing nitric oxide (NO) to nitrous oxide (N2O) to detoxify NO released by the human …
Controlling the reactivity of a metal-hydroxo adduct with a hydrogen bond
The enzymes manganese lipoxygenase (MnLOX) and manganese superoxide dismutase
(MnSOD) utilize mononuclear Mn centers to effect their catalytic reactions. In the oxidized …
(MnSOD) utilize mononuclear Mn centers to effect their catalytic reactions. In the oxidized …
Tris (2-pyridylmethyl) amines as emerging scaffold in supramolecular chemistry
Abstract tris-(2-Pyridylmethyl) amine (usually abbreviated as TPA or TPMA) are ligands
which are emerging in many fields of chemistry because of their ability to form stable and …
which are emerging in many fields of chemistry because of their ability to form stable and …
Theory Demonstrated a “Coupled” Mechanism for O2 Activation and Substrate Hydroxylation by Binuclear Copper Monooxygenases
P Wu, F Fan, J Song, W Peng, J Liu, C Li… - Journal of the …, 2019 - ACS Publications
Multiscale simulations have been performed to address the longstanding issue of “dioxygen
activation” by the binuclear copper monooxygenases (PHM and DβM), which have been …
activation” by the binuclear copper monooxygenases (PHM and DβM), which have been …
Sterically stabilized end-on superoxocopper (II) complexes and mechanistic insights into their reactivity with O–H, N–H, and C–H substrates
Instability of end-on superoxocopper (II) complexes, with respect to conversion to peroxo-
bridged dicopper (II) complexes, has largely constrained their study to very low …
bridged dicopper (II) complexes, has largely constrained their study to very low …