Organocopper compounds in organic chemistry appear most frequently in the form of
nucleophilic organocopper (I) reagents, which are used either as stoichiometric reagents or …

This review describes the additions of allylmagnesium reagents to carbonyl compounds and
to imines, focusing on the differences in reactivity between allylmagnesium halides and …

The stereochemical course of indium-promoted allylations to α-and β-oxy aldehydes has
been investigated in solvents ranging from anhydrous THF to pure H2O. The free hydroxyl …

The addition of organometallic reagents to imines bearing stereogenic N-substituents was
investigated by ourselves and many other groups. From the results of these studies it …

The stereochemical course of the 1, 2-addition of several allylmetal reagents and of the
Normant Grignard [ClMgO (CH2) 3MgCl] to 2-methoxycyclohexanone and …

The consequences of double diastereodifferentiation in chiral Lewis base catalyzed aldol
additions using chiral enoxysilanes derived from lactate, 3-hydroxyisobutyrate, and 3 …

The chelation-control model explains the high diastereoselectivity obtained in additions of
organometallic nucleophiles to α-alkoxy ketones but fails for reactions of allylmagnesium …

Highly efficient chiral ester enolate-imine condensation, giving 3, 4-disubstituted β-lactams
with excellent trans-syn or trans-anti diastereoselectivity, is reported. The chiral information …

Ynolates were found to react with α‐alkoxy‐, α‐siloxy‐, and α‐aryloxyketones at room
temperature to afford tetrasubstituted olefins with high Z selectivity. Since the geometrical …

Derivatives of three stereoisomeric hexodialdo-1, 5-pyranosides were reacted with four
Grignard C1 reagents: methoxymethyl-, allyloxymethyl-, benzyloxymethyl, and …