The electrochemical oxidation of amines is an essential alternative to the conventional
chemical transformation that provides critical routes for synthesising and modifying a wide …

Abstract N-Benzylmorpholine,-piperidine, and-pyrrolidine (1A-C, resp.) are oxidised by RuO
4 (generated in situ) at both endocyclic and exocyclic (benzylic) N—α-methylene positions to …

N, N-Dibenzylpiperazines have high affinity for sigma receptors, and we aimed to increase
their anticocaine activity by introducing substituents known to enhance such activity in other …

A large number of open-chain, macrocyclic, and hybrid complexes have been reported as
diagnostic, therapeutic, and theranostic agents. Lanthanide and transition-metal ions, which …

Following a suggestion by the late Lennart Eberson, we have employed the ICl–HFP (HFP
being hexafluoropropan-2-ol) system in iodination reactions, and found unambiguous …

Dibenzylpiperazine (1),-2-piperazinone (7),-2, 6-piperazinedione (9), and 1-benzoyl-4-
benzylpiperazine (30) were oxidized by RuO4 (generated in situ) by attack at their …

Abstract Treatment of N-benzylaziridine (1) with (aqua) xCu 2+ yields tetrabenzylcyclen 3 by
a metalassisted heterolytic (HETERO) pathway. Conversely, 1 is oxidised by the batho2Cu II …

The Whiffen effect in EPR spectroscopy and the relevant aspects of the H− C and M− C (M=
metal) hyperconjugation in radicals and spin-paired molecules has been reviewed. 1 A …

Over half of the small molecules approved for use in the USA by the FDA in 2012 contained
at least one nitrogen heterocycle. Of these, 11% contained a piperidine motif, emphasising …

This thesis describes a simple method for the synthesis of ethyleneimines. Ethyleneimines
have historically found use as cancer drugs as well as starting materials for amines, amides …