Expanding the Scope of Aluminum Chemistry with Noninnocent Ligands

LWT Parsons, LA Berben - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus Aluminum is the most abundant metal in the earth's crust at 8%, and it is also
widely available domestically in many countries worldwide, which ensures a stable supply …

Mechanistic Studies on the Bismuth‐Catalyzed Transfer Hydrogenation of Azoarenes

HW Moon, F Wang, K Bhattacharyya… - Angewandte …, 2023 - Wiley Online Library
Organobismuth‐catalyzed transfer hydrogenation has recently been disclosed as an
example of low‐valent Bi redox catalysis. However, its mechanistic details have remained …

Nitrogen monoxide and calix [4] pyrrolato aluminate: structural constraint enabled NO dimerization

SJ Kohl, LM Sigmund, M Schmitt, L Greb - Chemical Science, 2024 - pubs.rsc.org
The dimerization of nitrogen monoxide (NO) is highly relevant in homo-and heterogeneous
biochemical and environmental redox processes, but a broader understanding is …

Methanol-Mediated Hydrogen Transfer Reactions at Surface Lewis Acid Sites of H-SSZ-13

AE Enss, P Huber, PN Plessow… - The Journal of Physical …, 2024 - ACS Publications
Lewis acid sites (LAS) at the CHA (001) and CHA (101) surfaces are investigated regarding
their activity for MeOH-mediated hydrogen transfer reactions from MeOH to alkenes, yielding …

2-Anilidomethylpyridine-Derived Three-Coordinate Zinc Hydride: The Journey Unveils Anilide Backbone's Reactive Nature

C Mandal, S Joshi, S Das, S Mishra… - Inorganic …, 2023 - ACS Publications
Low-coordinate heteroleptic zinc hydrides are catalytically important but rare and
synthetically challenging. We herein report three-coordinate monomeric zinc hydride on a 2 …

Reversible O–H bond activation by tripodal tris (nitroxide) aluminum and gallium complexes

JS Scott, ML Maenaga, AJ Woodside, VW Guo… - Inorganic …, 2024 - ACS Publications
Herein, we report the preparation and characterization of the Group 13 metal complexes of a
tripodal tris (nitroxide)-based ligand, designated (TriNOx3–) M (M= Al (1), Ga (2), In (3)) …

Synthesis of Boron, Antimony, and Bismuth Diiminopyridine Complexes and Reactivity of Tris (Ortho-Carboranyl) Borane

JR Tidwell - 2023 - search.proquest.com
Diiminopyridines (DIMPYs) are a unique ligand class capable of multi-site substitution to fine
tune coordination. This ligand framework offers multiple binding modes and the potential for …

Synthesis and Reactivity of Aluminum (III) Complexes Supported by Non-Innocent Bis (enol) amine and Di (imino) pyridine Ligands

NA Phan - 2023 - search.proquest.com
This dissertation discusses the synthesis and characterization of aluminum (III)(Al 3+)
complexes with the non-innocent ligands bis (enol) amine (H 3 ONO) and di (imino) pyridine …