New strategies for the transition-metal catalyzed synthesis of aliphatic amines

A Trowbridge, SM Walton, MJ Gaunt - Chemical reviews, 2020 - ACS Publications
Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …

Applied hydroformylation

R Franke, D Selent, A Börner - Chemical reviews, 2012 - ACS Publications
Hydroformylation is the addition of synthesis gas (“syngas”), a mixture of CO and H2, to
olefins in the presence of a catalyst under the formation of aldehydes. Hydrogen (“hydro”) …

Tandem Hydroaminomethylation reaction to synthesize amines from alkenes

P Kalck, M Urrutigoïty - Chemical Reviews, 2018 - ACS Publications
In the context of atom economy and low environmental impact, synthesis of amines by an
efficient catalytic process is of great importance to produce these building blocks for fine …

Recent advances in amine synthesis by catalytic hydroaminomethylation of alkenes

D Crozet, M Urrutigoïty, P Kalck - ChemCatChem, 2011 - Wiley Online Library
Carbon–carbon coupling catalyzed by transition metals represents a powerful synthetic
method to have an access to organic molecules, especially when they present a significant …

Diene hydroaminomethylation via ruthenium-catalyzed C–C bond forming transfer hydrogenation: beyond carbonylation

S Oda, J Franke, MJ Krische - Chemical Science, 2016 - pubs.rsc.org
Under the conditions of ruthenium catalyzed transfer hydrogenation using 2-propanol as
terminal reductant, 1, 3-dienes engage in reductive C–C coupling with formaldimines …

Hydroaminomethylation Beyond Carbonylation: Allene–Imine Reductive Coupling by Ruthenium‐Catalyzed Transfer Hydrogenation

S Oda, B Sam, MJ Krische - Angewandte Chemie, 2015 - Wiley Online Library
Ruthenium (II)‐catalyzed hydrogen transfer from 2‐propanol mediates reductive coupling of
1, 1‐disubstituted allenes with formaldimines with complete branch‐regioselectivity, thus …

Mild Pd-Catalyzed N-Arylation of Methanesulfonamide and Related Nucleophiles: Avoiding Potentially Genotoxic Reagents and Byproducts

BR Rosen, JC Ruble, TJ Beauchamp, A Navarro - Organic Letters, 2011 - ACS Publications
A convenient, general, and high yielding Pd-catalyzed cross-coupling of
methanesulfonamide with aryl bromides and chlorides is reported. The use of this method …

Recent progress in rhodium-catalyzed hydroaminomethylation

C Chen, XQ Dong, X Zhang - Organic Chemistry Frontiers, 2016 - pubs.rsc.org
Hydroaminomethylation is a perfect reaction for converting alkenes into valuable amines
with high atom economy in the presence of the syngas and amines. Significant progress has …

Recent advances in catalytic C–N bond formation: a comparison of cascade hydroaminomethylation and reductive amination reactions with the corresponding …

S Raoufmoghaddam - Organic & Biomolecular Chemistry, 2014 - pubs.rsc.org
The design and catalytic implementation of tandem reactions to selectively create nitrogen-
containing products under mild conditions has encountered numerous challenges in …

Efficient and regioselective ruthenium-catalyzed hydro-aminomethylation of olefins

L Wu, I Fleischer, R Jackstell… - Journal of the American …, 2013 - ACS Publications
An efficient and regioselective ruthenium-catalyzed hydroaminomethlyation of olefins is
reported. Key to success is the use of specific 2-phosphino-substituted imidazole ligands …