Bifunctional iron-catalyzed alkyne Z-selective hydroalkylation and tandem Z-E inversion via radical molding and flipping
Y Zhang, D Fu, Z Chen, R Cui, W He, H Wang… - Nature …, 2024 - nature.com
The challenging synthesis of thermodynamic-unfavored cis-olefins through catalytic cross-
coupling reactions requires the synergistic interaction of substrate-activating units and …
coupling reactions requires the synergistic interaction of substrate-activating units and …
Iron in Organometallic Transformations: A Sustainable Substitute for Noble Metals
Transition metal catalysis plays a pivotal role in chemical synthesis. Noble metals often grab
significant attention in organometallic catalysis due to their high reactivity. However, the …
significant attention in organometallic catalysis due to their high reactivity. However, the …
Iron-catalyzed (E)-selective hydrosilylation of alkynes: scope and mechanistic insights
Iron-catalyzed hydrosilylation of internal alkynes has been rarely reported. Even in these
rare cases, additives have been used for the success of the reaction, which often creates a …
rare cases, additives have been used for the success of the reaction, which often creates a …
Iron-Catalyzed Chemoselective Transfer Hydrogenation of α,β-Unsaturated Ketones Using H2O as a Surrogate of Hydrogen
Sustainable and highly economical iron-catalyzed chemoselective reduction of C═ C of α, β-
unsaturated ketones has been established under mild reaction protocols. Water is used as a …
unsaturated ketones has been established under mild reaction protocols. Water is used as a …
Heterometallic Mg‐Ni‐Mg Complex Promoted Hydrosilylation of Alkenes: Catalytic Performance and Intermediates Characterization†
Y Cai, S Jiang, X Xu - Chinese Journal of Chemistry, 2024 - Wiley Online Library
Comprehensive Summary Heteronuclear metal complexes have played an increasingly
important role in both small molecules activation and catalytic transformation due to the …
important role in both small molecules activation and catalytic transformation due to the …