Recent years have witnessed an increase in the popularity of α-boryl organometallic
reagents as versatile nucleophiles in asymmetric synthesis. These compounds have been …

Abstract Skipped dienes (1, 4‐dienes) are widely distributed in a variety of biologically active
natural products. The synthesis of these skipped dienes is a relatively undeveloped area …

Enantioenriched 1, 1-silylboryl alkanes possess silyl and boryl groups that are both
connected to the same stereogenic carbon center at well-defined orientations. As these …

The first dynamic kinetic asymmetric transformation of racemic biaryl substrates on the basis
of axial-to-central chirality transfer has been realized. Chiral Pd-NHC complexes were found …

The development of a gold (III) catalyzed direct enantioconvergent 1, 5-enyne
cycloisomerization and kinetic resolution reaction is described. The transformation results in …

An approach for the copper-catalyzed synthesis of enantioenriched amides bearing an α-
stereogenic center is disclosed. This method involves the addition of an allyl copper species …

The development of α, α-disubstituted crotylboronate reagents is reported. Chiral Brønsted
acid-catalyzed asymmetric aldehyde addition with the developed E-crotylboron reagent …

Catalytic asymmetric hydroboration of unsaturated bonds has been recognized as the most
straightforward method for the construction of chiral organoboron compounds. Although …

The copper-catalyzed highly selective hydrosilylation of silyl or boryl alkene has been
developed. This chemistry could afford a practical method for preparing chiral geminated …

Chiral organoborons are of great value in asymmetric synthesis, functional materials, and
medicinal chemistry. The development of chiral bis (boryl) alkanes, especially optically …