Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Cucurbiturils‐mediated noble metal nanoparticles for applications in sensing, sers, theranostics, and catalysis

LL Tan, M Wei, L Shang… - Advanced Functional …, 2021 - Wiley Online Library
Noble metal nanoparticles (NMNPs), which spring up like mushrooms, are gaining
momentum owing to their unique physicochemical characteristics. Cucurbiturils, a class of …

Atomic-precision Pt6 nanoclusters for enhanced hydrogen electro-oxidation

X Wang, L Zhao, X Li, Y Liu, Y Wang, Q Yao… - Nature …, 2022 - nature.com
The discord between the insufficient abundance and the excellent electrocatalytic activity of
Pt urgently requires its atomic-level engineering for minimal Pt dosage yet maximized …

Eight-Electron Superatomic Cu31 Nanocluster with Chiral Kernel and NIR-II Emission

T Jia, ZJ Guan, C Zhang, XZ Zhu, YX Chen… - Journal of the …, 2023 - ACS Publications
Owing to the inherent instability caused by the low Cu (I)/Cu (0) half-cell reduction potential,
Cu (0)-containing copper nanoclusters are quite uncommon in comparison to their Ag and …

Supercrystal engineering of atomically precise gold nanoparticles promoted by surface dynamics

Q Yao, L Liu, S Malola, M Ge, H Xu, Z Wu, T Chen… - Nature Chemistry, 2023 - nature.com
The controllable packing of functional nanoparticles (NPs) into crystalline lattices is of
interest in the development of NP-based materials. Here we demonstrate that the size …

Chemically modified gold/silver superatoms as artificial elements at nanoscale: design principles and synthesis challenges

S Takano, T Tsukuda - Journal of the American Chemical Society, 2021 - ACS Publications
Pure and doped gold/silver clusters protected by monolayers of organic ligands have
attracted much interest as novel functional materials owing to their nonbulk-like, size-specific …

Body-Centered-Cubic-Kernelled Ag15Cu6 Nanocluster with Alkynyl Protection: Synthesis, Total Structure, and CO2 Electroreduction

G Deng, J Kim, MS Bootharaju, F Sun… - Journal of the …, 2022 - ACS Publications
While atomically monodisperse nanostructured materials are highly desirable to unravel the
size-and structure-catalysis relationships, their controlled synthesis and the atomic-level …

Atomically Precise Silver Clusters Stabilized by Lacunary Polyoxometalates with Photocatalytic CO2 Reduction Activity

Y Feng, F Fu, L Zeng, M Zhao, X Xin… - Angewandte Chemie …, 2024 - Wiley Online Library
The syntheses of atomically precise silver (Ag) clusters stabilized by multidentate lacunary
polyoxometalate (POM) ligands have been emerging as a promising but challenging …

Correlations between the fundamentals and applications of ultrasmall metal nanoclusters: Recent advances in catalysis and biomedical applications

Z Liu, Z Wu, Q Yao, Y Cao, OJH Chai, J Xie - Nano Today, 2021 - Elsevier
Ultrasmall metal nanoparticles (NPs) with a well-defined composition and structure, the so-
called metal nanoclusters (NCs, usually smaller than 3 nm in size), represent the forefront …

Atomically Precise Au42 Nanorods with Longitudinal Excitons for an Intense Photothermal Effect

Y Li, Y Song, X Zhang, T Liu, T Xu… - Journal of the …, 2022 - ACS Publications
Metallic-state gold nanorods are well known to exhibit strong longitudinal plasmon
excitations in the near-infrared region (NIR) suitable for photothermal conversion. However …