Photocatalytic late-stage C–H functionalization

P Bellotti, HM Huang, T Faber, F Glorius - Chemical Reviews, 2023 - ACS Publications
The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …

Electrochemical late-stage functionalization

Y Wang, S Dana, H Long, Y Xu, Y Li… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …

Photoelectrochemical asymmetric catalysis enables site-and enantioselective cyanation of benzylic C–H bonds

CY Cai, XL Lai, Y Wang, HH Hu, J Song, Y Yang… - Nature Catalysis, 2022 - nature.com
The enantioselective functionalization of ubiquitous C (sp 3)–H bonds is ideally suited for
the construction of three-dimensional chiral structures. However, organic molecules often …

Direct photocatalyzed hydrogen atom transfer (HAT) for aliphatic C–H bonds elaboration

L Capaldo, D Ravelli, M Fagnoni - Chemical Reviews, 2021 - ACS Publications
Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

Technological innovations in photochemistry for organic synthesis: flow chemistry, high-throughput experimentation, scale-up, and photoelectrochemistry

L Buglioni, F Raymenants, A Slattery… - Chemical …, 2021 - ACS Publications
Photoinduced chemical transformations have received in recent years a tremendous amount
of attention, providing a plethora of opportunities to synthetic organic chemists. However …

Recent applications of homogeneous catalysis in electrochemical organic synthesis

X Cheng, A Lei, TS Mei, HC Xu, K Xu… - CCS Chemistry, 2022 - chinesechemsoc.org
Although the combination of electrochemistry and homogeneous catalysis has proven to be
a powerful strategy for achieving a diverse array of novel transformations, some challenges …

Electrophotocatalysis: combining light and electricity to catalyze reactions

H Huang, KA Steiniger, TH Lambert - Journal of the American …, 2022 - ACS Publications
Visible-light photocatalysis and electrocatalysis are two powerful strategies for the promotion
of chemical reactions that have received tremendous attention in recent years. In contrast …

Electrocatalysis as an enabling technology for organic synthesis

LFT Novaes, J Liu, Y Shen, L Lu… - Chemical Society …, 2021 - pubs.rsc.org
Electrochemistry has recently gained increased attention as a versatile strategy for
achieving challenging transformations at the forefront of synthetic organic chemistry …

Radical C(sp3)–H functionalization and cross-coupling reactions

DL Golden, SE Suh, SS Stahl - Nature Reviews Chemistry, 2022 - nature.com
C–H functionalization reactions are playing an increasing role in the preparation and
modification of complex organic molecules, including pharmaceuticals, agrochemicals and …

Photoelectrochemical asymmetric catalysis enables enantioselective heteroarylcyanation of alkenes via C–H functionalization

XL Lai, HC Xu - Journal of the American Chemical Society, 2023 - ACS Publications
The asymmetric difunctionalization of alkenes, a method transforming readily accessible
alkenes into enantioenriched chiral structures of high value, has long been a focal point of …