Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …

Precious metals are key in various fields of research and precious metal nanomaterials are
directly relevant for optics, catalysis, pollution management, sensing, medicine, and many …

Transition-metal-catalyzed branched and enantioselective allylic substitution of
monosubstituted precursors with carbon, nitrogen, oxygen, sulfur, and fluoride nucleophiles …

Activation of H–H, Si–H, and C–H bonds through σ-bond coordination has grown in the past
30 years from a scientific curiosity to an important tool in the functionalization of …

Secondary phosphine oxides present tautomeric equilibrium between the pentavalent oxide
form (SPO) and the trivalent phosphinous acid (PA). This dichotomy is the origin of the rich …

Metal complexes of secondary phosphine oxides (SPOs) were introduced as homogeneous
catalysts in the 1980s for hydroformylation and hydrogenation with platinum as the metal. As …

The present article defines the state-of-the-art of iridium nano catalyst. In this article, the
attempts are made to discuss the syntheses, characterizations, applications, toxicity and …

The heterolytic cleavage of H2 into H+ and H−, and the subsequent transfer of these
hydrogen species to polarized CX groups, is a useful strategy to obtain high selectivities in …

A series of ruthenium nanoparticles (Ru NPs) bearing different ligands on their surfaces
have been used as catalysts in the selective hydrogenation of nitrobenzene to …

C–H arylations of oxazolines were accomplished with a well‐defined palladium catalyst
derived from a secondary bisdiamantyl phosphine oxide. The single‐component secondary …