Oligosaccharides are the ubiquitous molecules of life. In order to translate human
bioglycosylation into clinical applications, homogeneous samples of oligosaccharides and …

Novel synthetic methods published since 2005 affording carbohydrates containing sulfur
atom (s) are reviewed. The review is divided to subchapters based on the position of sulfur …

An efficient and stereoretentive copper-catalyzed cross-coupling of glycosyl thiosulfonate
and boronic acid for the construction of thioglycosides is described. The good functional …

Unsymmetrical sulfides are widely found in the pharmaceutical industry, organic synthesis,
and materials science. As a result, it will be of great significance to discover mild and …

A green method to construct C–S bonds using sulfonyl chlorides and alcohols/acids via a
PIII/PV═ O catalytic system is reported. The organophosphorus-catalyzed umpolung …

The nonbasic synthesis of unsymmetrical thioethers via nickel-catalyzed reductive thiolation
between aryl (hetero) iodides and N-thioimides is illustrated. N-Bromosuccinimide (NBS) …

Glycosylation is an important strategy to improve the druggability of lead compounds. Here,
we present a palladium-catalysed stereospecific N-glycosylation of sulfonamides. This …

A highly efficient, palladium-catalyzed glycosylation between 3, 4-O-carbonate glycals and
acid-labile oximes is disclosed. This approach features broad substrate scope, high …

Chemoselective transformations of functionalized sulfonyl fluorides and chlorides are
surveyed comprehensively. It is shown that sulfonyl fluorides provide an excellent selectivity …

Isatindigotindolosides, indoles containing a 1-S-β-glucopyranosyl unit at position C2, show
promising bioactivity. Here, we report a copper-catalyzed C2-or C3-thioglycosylation of …