Phenalenyl, a zigzag-edged odd alternant hydrocarbon unit can be found in the graphene
nanosheet. Hückel molecular orbital calculations indicate the presence of a nonbonding …

Many reactions have been discovered that lead to coupling of haloarenes to arenes using
potassium tert-butoxide as the base, and one of a variety of organic compounds as an …

We herein report a novel square-planar complex [CoIIL], which was synthesized using the
electronically interesting phenalenyl-derived ligand LH2= 9, 9′-(ethane-1, 2-diylbis …

Herein, we have established a phenalenyl-based molecular scaffold which serves as a
potent photoreductant utilizing the empty NBMO in the presence of a base to form a radical …

Closed-shell phenalenyl (PLY) systems are increasingly becoming more attractive as
building blocks for developing promising catalysts and electroactive cathode materials, as …

Phenalenyl-based molecules can switch their redox states on successive addition of
electrons from a cation to a radical to an anion. Utilizing this phenomenal ability, we have …

We report a manganese-catalyzed hydrosilylative reduction of various primary amides to
amines (25 examples). On simple modification of the reaction conditions such as in the …

Borrowing hydrogen from alcohols, storing it on a catalyst and subsequent transfer of the
hydrogen from the catalyst to an in situ generated imine is the hallmark of a transition metal …

Biaryl and heterobiaryl-containing cyclic peptides represent promising scaffolds for the
development of bioactive molecules. The incorporation of heterobiaryl motifs continues to …

In this report, nickel-catalyzed hydroboration of vinylarenes and aliphatic alkenes is
investigated. The non-innocent phenalenyl ligand moiety in the nickel complex Ni (PLY) 2 …