Ionic liquids and their interaction with cellulose

A Pinkert, KN Marsh, S Pang, MP Staiger - Chemical reviews, 2009 - ACS Publications
Sustainability, industrial ecology, eco-efficiency, and green chemistry are directing the
development of the next generation of materials, products, and processes. Biodegradable …

Dissolution of lignocellulosic materials and its constituents using ionic liquids—a review

P Mäki-Arvela, I Anugwom, P Virtanen… - Industrial Crops and …, 2010 - Elsevier
The state of art from the dissolution of cellulose, lignin and wood using ionic liquids is
presented in this work. The emphasis is put on the relationship between the properties of …

Pyridinium N-Phenolate Betaine Dyes

VG Machado, RI Stock, C Reichardt - Chemical reviews, 2014 - ACS Publications
It is well-known that the solvent can strongly influence the course, rate, and equilibrium
position of many chemical reactions. 1, 2 The position and intensity of the bands in the …

Review of cellulose non-derivatizing solvent interactions with emphasis on activity in inorganic molten salt hydrates

S Sen, JD Martin, DS Argyropoulos - ACS Sustainable Chemistry …, 2013 - ACS Publications
During cellulose dissolution in non-derivatizing solvents, the inter-and intramolecular
hydrogen bonds of the polymer are deconstructed. This occurs either by hydrogen bond …

Applications of ionic liquids in carbohydrate chemistry: a window of opportunities

OA El Seoud, A Koschella, LC Fidale, S Dorn… - …, 2007 - ACS Publications
Ionic liquids (ILs) are composed only of ions. Of special interest to this review are those
where at least one ion (the cation) is organic and whose melting points are below or not far …

Superior solubility of polysaccharides in low viscosity, polar, and halogen-free 1, 3-dialkylimidazolium formates

Y Fukaya, A Sugimoto, H Ohno - Biomacromolecules, 2006 - ACS Publications
We successfully prepared low viscosity, polar, and halogen-free ionic liquids as potential
solvents for a wide range of polysaccharides. A series of 1, 3-dialkylimidazolium formates …

Twenty-five years of cellulose chemistry: Innovations in the dissolution of the biopolymer and its transformation into esters and ethers

M Kostag, M Gericke, T Heinze, OA El Seoud - Cellulose, 2019 - Springer
The anniversary of the journal “Cellulose” is an opportunity to review innovations that were
introduced during the past 25 years. Of these, from our perspective, the development of …

Role of solvent parameters in the regeneration of cellulose from ionic liquid solutions

LKJ Hauru, M Hummel, AWT King… - …, 2012 - ACS Publications
The ionic liquids 1-ethyl-3-methylimidazolium acetate [emim] OAc, N, N, N, N-
tetramethylguanidium propionate [TMGH] EtCO2, and N, N, N, N-tetramethylguanidium …

Cellulose solvents–remarkable history, bright future

T Liebert - Cellulose solvents: for analysis, shaping and chemical …, 2010 - ACS Publications
The paper summarizes different approaches for the dissolution of cellulose and the use of
these cellulose solutions for analysis, regeneration, and homogeneous modification of the …

Reflections on the solubility of cellulose

A Pinkert, KN Marsh, S Pang - Industrial & Engineering Chemistry …, 2010 - ACS Publications
Wood cellulose can be used for producing biofuels and biopolymers, thus offering a solution
to global concerns on the excessive use of fossil fuels. This requires a cellulose solvent that …