Use of chiral sulfoxides in asymmetric synthesis

H Pellissier - Tetrahedron, 2006 - Elsevier
Although the first chiral organosulfur compounds were obtained at the beginning of this
century, they have received more attention since the early 1960s. Initially, chiral sulfur …

Sulfoxides and disulfides from sulfenic acids: Synthesis and applications

CMA Gangemi, E D'Agostino, MC Aversa, A Barattucci… - Tetrahedron, 2023 - Elsevier
Sulfur-based functional groups are found in a broad range of natural products and
therapeutic compounds. The sulfoxide moiety is present in a significant portion of …

Total synthesis of (−)-strictosidine and interception of aryne natural product derivatives “strictosidyne” and “strictosamidyne”

SM Anthony, V Tona, Y Zou, LA Morrill… - Journal of the …, 2021 - ACS Publications
Monoterpene indole alkaloids are a large class of natural products derived from a single
biosynthetic precursor, strictosidine. We describe a synthetic approach to strictosidine that …

The chemistry of α, β-unsaturated sulfoxides and sulfones: An update

I Forristal - Journal of Sulfur Chemistry, 2005 - Taylor & Francis
A comprehensive review of recent chemistry of α, β-unsaturated sulfoxides and sulfones is
presented. Emphasis has been placed on new reactions and strategies, stereo-and enantio …

Thermolysis-induced two-or multicomponent tandem reactions involving isocyanides and sulfenic-acid-generating sulfoxides: Access to diverse sulfur-containing …

S Wu, X Lei, E Fan, Z Sun - Organic letters, 2018 - ACS Publications
Direct reaction of isocyanides with some sulfenic-acid-generating sulfoxides led to the
effective formation of the corresponding thiocarbamic acid S-esters in good to high yields. A …

Enantiodivergent Synthesis of Pyrrolo[2,1-a]isoquinolines Based on Diastereoselective Parham Cyclization and α-Amidoalkylation Reactions

I González-Temprano, I Osante, E Lete… - The Journal of …, 2004 - ACS Publications
Enantiodivergent synthesis of C-10b-substituted pyrrolo [2, 1-a] isoquinolines starting from
an enantiomerically pure N-phenethylnorborn-5-en-endo-2, 3-dicarboxyimide 3a, with a 2 …

New glycomimetics: anomeric sulfonates, sulfenamides, and sulfonamides

S Knapp, E Darout, B Amorelli - The Journal of Organic Chemistry, 2006 - ACS Publications
The synthesis of a variety of new 1-thio-d-glucopyranose derivatives oxidized at the sulfur
atom is described, including seven 1-C-sulfonic acids, three sulfonate esters, three sulfinate …

Glycosulfoxides in carbohydrate chemistry

MC Aversa, A Barattucci, P Bonaccorsi - Tetrahedron, 2008 - Elsevier
Organic molecules including sulfur atoms are widespread in biological systems or in the
pharmaceutical industry, and therefore play a significant role in synthetic organic chemistry …

Synthesis of Various α‐Substituted Alkenyl Sulfoxides from Alkynes and β‐Sulfinyl Esters

AV Kalyanakrishnan, A Joshy, AK Arya… - …, 2021 - Wiley Online Library
Methods to synthesize α‐substituted alkenyl sulfoxides are highly useful as they are widely
used to construct diverse molecules of high synthetic importance. We have described a …

Transient sulfenic acids in the synthesis of biologically relevant products

A Barattucci, MC Aversa, A Mancuso, TMG Salerno… - Molecules, 2018 - mdpi.com
Sulfenic acids as small molecules are too unstable to be isolated and their transient nature
offers the possibility to involve them in concerted processes that lead to the obtainment of …