Chirality sensing using stereodynamic probes with distinct electronic circular dichroism output

C Wolf, KW Bentley - Chemical Society Reviews, 2013 - pubs.rsc.org
Circular dichroism (CD) spectroscopy is one of the most useful techniques for the
stereochemical analysis of chiral biopolymers and fine chemicals. It has become invaluable …

Circular dichroism sensing: Strategies and applications

JSSK Formen, JR Howard, EV Anslyn… - Angewandte Chemie …, 2024 - Wiley Online Library
The analysis of the absolute configuration, enantiomeric composition, and concentration of
chiral compounds are frequently encountered tasks across the chemical and health …

Optical analysis of reaction yield and enantiomeric excess: a new paradigm ready for prime time

BT Herrera, SL Pilicer, EV Anslyn… - Journal of the …, 2018 - ACS Publications
This Perspective highlights the advances of optical methods for asymmetric reaction
discovery. Optical analysis allows for the determination of absolute configuration …

Data-driven prediction of circular dichroism-based calibration curves for the rapid screening of chiral primary amine enantiomeric excess values

JR Howard, A Bhakare, Z Akhtar, C Wolf… - Journal of the …, 2022 - ACS Publications
Here, we describe the prediction of the circular dichroism (CD) response of a three-
component chiroptical sensor for enantiomeric excess (ee) determination of chiral amines …

Rapid optical methods for enantiomeric excess analysis: From enantioselective indicator displacement assays to exciton-coupled circular dichroism

HH Jo, CY Lin, EV Anslyn - Accounts of Chemical Research, 2014 - ACS Publications
Conspectus The advent of high-throughput screening (HTS) for chiral catalysts has
encouraged the development of fast methods for determining enantiomeric excess (ee) …

Ligand-modulated conformational switching in a fully synthetic membrane-bound receptor

FGA Lister, BAF Le Bailly, SJ Webb, J Clayden - Nature Chemistry, 2017 - nature.com
Signal transduction through G-protein-coupled receptors (GPCRs) involves binding to
signalling molecules at the cell surface, which leads to global changes in molecular …

Molecular Recognition and Chirality Sensing of Epoxides in Water Using Endo-Functionalized Molecular Tubes

LL Wang, Z Chen, WE Liu, H Ke… - Journal of the …, 2017 - ACS Publications
Chiral epoxides are important intermediates in chemistry and biology. The high-throughput
screening of asymmetric epoxidation conditions requires fast determination of the absolute …

A Self‐Assembled Cage for Wide‐Scope Chiral Recognition in Water

G Wu, Y Chen, S Fang, L Tong, L Shen… - Angewandte Chemie …, 2021 - Wiley Online Library
Herein, we report the self‐assembly of an anionic homochiral octahedral cage by
condensing six Ga3+ cations and four trisacylhydrazone ligands. The robust nature of the …

Homochiral MOF as circular dichroism sensor for enantioselective recognition on nature and chirality of unmodified amino acids

YW Zhao, Y Wang, XM Zhang - ACS applied materials & interfaces, 2017 - ACS Publications
Self-assembly of zinc salt with rationally designed chiral ligand,(1 R, 2 R)-2-(pyridine-4-
ylcarbamoyl) cyclohexanecarboxylic acid (RR-PCCHC) generated 2D homochiral metal …

Chiral copper (i)–organic frameworks for dye degradation and the enantioselective recognition of amino acids

J Zhao, J Luo, Z Lin, X Chen, GH Ning… - Inorganic Chemistry …, 2022 - pubs.rsc.org
Covalent metal–organic frameworks (CMOFs) are a novel class of porous materials made by
combining the chemistry of metal–and covalent organic frameworks (MOFs and COFs) and …