Organic photoredox catalysis

NA Romero, DA Nicewicz - Chemical reviews, 2016 - ACS Publications
In this review, we highlight the use of organic photoredox catalysts in a myriad of synthetic
transformations with a range of applications. This overview is arranged by catalyst class …

Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis

CK Prier, DA Rankic, DWC MacMillan - Chemical reviews, 2013 - ACS Publications
1. INTRODUCTION A fundamental aim in the field of catalysis is the development of new
modes of small molecule activation. One approach toward the catalytic activation of organic …

Iron-Complex-Based Supramolecular Framework Catalyst for Visible-Light-Driven CO2 Reduction

K Kosugi, C Akatsuka, H Iwami, M Kondo… - Journal of the …, 2023 - ACS Publications
Molecule-based heterogeneous photocatalysts without noble metals are one of the most
attractive systems for visible-light-driven CO2 reduction. However, reports on this class of …

[HTML][HTML] Sacrificial electron donor reagents for solar fuel production

Y Pellegrin, F Odobel - Comptes Rendus Chimie, 2017 - Elsevier
Although justly considered as a cumbersome component in artificial photosystems, these
simple molecules are a “necessary evil” to drive photo-induced reactions aiming at …

[HTML][HTML] Photocatalytic reduction of CO2 using metal complexes

Y Yamazaki, H Takeda, O Ishitani - Journal of Photochemistry and …, 2015 - Elsevier
Developing photocatalytic systems for CO 2 reduction will provide useful and energy-rich
compounds and would be one of the most important focuses in the field of “artificial …

Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy

W Xie, J Xu, U Md Idros, J Katsuhira, M Fuki… - Nature Chemistry, 2023 - nature.com
Increasing levels of CO2 in the atmosphere is a problem that must be urgently resolved if the
rise in current global temperatures is to be slowed. Chemically reducing CO2 into …

Visible‐light photoredox catalysis

J Xuan, WJ Xiao - Angewandte Chemie International Edition, 2012 - Wiley Online Library
In the last few years, visible‐light initiated organic transformations have attracted increasing
attention. The development of visible‐light‐promoted photocatalytic reactions, which enable …

Reaction mechanisms of catalytic photochemical CO2 reduction using Re (I) and Ru (II) complexes

Y Kuramochi, O Ishitani, H Ishida - Coordination Chemistry Reviews, 2018 - Elsevier
Reduction of CO 2 is one of the most important reactions that might solve the problems of
global warming and shortage of fossil-fuel resources simultaneously. Metal complex …

Ketone–olefin coupling of aliphatic and aromatic carbonyls catalyzed by excited-state acridine radicals

NJ Venditto, YS Liang, RK El Mokadem… - Journal of the …, 2022 - ACS Publications
Ketone–olefin coupling reactions are common methods for the formation of carbon–carbon
bonds. This reaction class typically requires stoichiometric or super stoichiometric quantities …

Visible light photoredox catalysis: applications in organic synthesis

JMR Narayanam, CRJ Stephenson - Chemical Society Reviews, 2011 - pubs.rsc.org
The use of visible light sensitization as a means to initiate organic reactions is attractive due
to the lack of visible light absorbance by organic compounds, reducing side reactions often …