N-heterocyclic carbene adducts of main group elements and their use as ligands in transition metal chemistry

A Doddi, M Peters, M Tamm - Chemical reviews, 2019 - ACS Publications
N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …

A highly selective naphthalene-fluorophore salamo-based chemosensor for sequential identification of Cu2+ and S2− ions in water applications

SS Feng, YX Wei, M Li, WK Dong - Journal of Molecular Structure, 2022 - Elsevier
Two new fluorescent chemical sensors, H 4 L and its L-Cu 2+ complex, are reported for the
selective detection of Cu 2+ and S 2− ions in DMF solution, respectively. In the fluorescent …

A Sensitive Water-Soluble Reversible Optical Probe for Hg2+ Detection

S Das, A Sarkar, A Rakshit, A Datta - Inorganic Chemistry, 2018 - ACS Publications
We report the serendipitous discovery of an optical mercury sensor while trying to develop a
water-soluble manganese probe. The sensor is based on a pentaaza macrocycle …

A carbonothioate-based far-red fluorescent probe for the specific detection of mercury ions in living cells and zebrafish

Q Duan, H Zhu, C Liu, R Yuan, Z Fang, Z Wang, P Jia… - Analyst, 2019 - pubs.rsc.org
The detection of ionic mercury (Hg2+) is very important because it is a highly toxic
environmental pollutant that could cause serious diseases and threaten human health …

A new monomeric octahedral cadmium (II) complex based on 1, 1-bis (3-methyl-4-imidazoline-2-thione) methane ligand with dye adsorption ability

M Bahrani-Pour, A Beheshti, T Sedaghat… - Journal of Sulfur …, 2024 - Taylor & Francis
A new cadmium complex with a flexible imidazolinethione ligand has been successfully
synthesized. The ligand acts as a bidentate chelating molecule, resulting in the structure …

Impact of coordination ability of the selected anions on tuning the structure of Hg (II) complexes constructed from a neutral dithione ligand: Iodine uptake and DFT …

A Beheshti, M Bahrani-Pour, S Samiee, P Mayer - Inorganica Chimica Acta, 2022 - Elsevier
In view to examine the role of coordination potential of the selected anions on architect of
complexes, HgL 2](ClO 4) 2 (C 1) and [HgL 2](PF 6) 2 (C 2) were synthesized with a HgS 4 …

Hg–C bond protonolysis by a functional model of bacterial enzyme organomercurial lyase MerB

R Karri, R Das, RK Rai, A Gopalakrishnan… - Chemical …, 2020 - pubs.rsc.org
Herein, we report a novel synthetic compound 1, having a highly nucleophilic selenolate
(Se−) moiety and a thiol (–SH) functional group, which showed efficient Hg–C bond …

Synthesis, structures and DFT study of copper coordination with bis-benzimidazole based thiones and selones: Scope for nonstoichiometric Cu2-xSe nanoparticles

RK Rai, A Chalana, R Karri, A Islam, RS Pati… - Inorganica Chimica …, 2024 - Elsevier
The newly synthesized benzimidazole-based [E2]-donor ligands (E= S or Se)(L1− L4) on
reaction with copper (II) chloride and copper (II) acetate involved reduction of Cu (II) to Cu (I) …

Tuning the structure of mercury (II) complexes as antibacterial agents by varying the halogen atoms (Cl and Br) and extending the spacer length of the imidazole-2 …

A Beheshti, ES Mousavifard, M Kubicki… - Inorganica Chimica …, 2021 - Elsevier
A series of mercury (II) complexes with empirical formula of Hg 2 LX 4 (L= ligand and X=
halogen) namely [Hg 2 (mbit) Cl 4] n (1),{[Hg₂ (mbit) Br₄]· CH 3 CN} n (2)[mbit= bis (1 …

A greener approach towards the synthesis of N-heterocyclic thiones and selones using the mechanochemical technique

S Rangarajan, HS Kunchur, MS Balakrishna - Dalton Transactions, 2022 - pubs.rsc.org
This manuscript describes the synthesis of N-heterocyclic thiones and selones of a variety of
imidazolium salts involving an eco-friendly and solventless ball-milling technique. The …