[HTML][HTML] Recent advances in polycaprolactones for anticancer drug delivery

A Bhadran, T Shah, GK Babanyinah, H Polara… - Pharmaceutics, 2023 - mdpi.com
Poly (ε-Caprolactone) s are biodegradable and biocompatible polyesters that have gained
considerable attention for drug delivery applications due to their slow degradation and ease …

Neodymium catalysts for polymerization of dienes, vinyl monomers, and ε-caprolactone

H Wang, JMO Cue, EL Calubaquib, RN Kularatne… - Polymer …, 2021 - pubs.rsc.org
Among the rare-earth catalysts, neodymium-based catalysts are systematically investigated
due to their efficiency and versatility. Still, the correlation between the complex structure and …

Ring opening polymerization and copolymerization of L‐lactide and ɛ‐caprolactone by bis‐ligated magnesium complexes

RM Slattery, AE Stahl, KR Brereton… - Journal of Polymer …, 2019 - Wiley Online Library
ABSTRACT Seven magnesium complexes (1–7) were synthesized by reaction of new (L 3‐
H–L 5‐H) and previously reported ketoimine pro‐ligands with dibutyl magnesium and were …

[HTML][HTML] A perspective into ring-opening polymerization of ε-caprolactone and lactides: effect of, ligand, catalyst structure and system dynamics, on catalytic activity …

WA Munzeiwa, BO Omondi, VO Nyamori - Polymer Bulletin, 2024 - Springer
Polylactic acid (PLAs) and polycaprolactones (PCLs) are emerging to be polyesters of
choice because they are biodegradable and biocompatible. The industrial viable method …

A binary neodymium catalyst for the polymerization of lactones

RN Kularatne, S Taslimy, A Bhadran, JMO Cue… - Polymer …, 2023 - pubs.rsc.org
Polylactones are widely used in biomedical applications and for drug delivery due to their
biocompatibility and biodegradability. Polylactones are produced by the ring-opening …

Highly active tridentate amino-phenol zinc complexes for the catalytic ring-opening polymerization of ε-caprolactone

Q Hu, S Jie, P Braunstein, BG Li - Journal of Organometallic Chemistry, 2019 - Elsevier
Abstract Tridentate 2, 6-bis (imino) phenol (L1− L4) and 2, 6-bis (amino) phenol (L5− L8)
ligands and their corresponding zinc chloride complexes (1–8) have been synthesized and …

[HTML][HTML] Halide-free neodymium phosphate based catalyst for highly cis-1, 4 selective polymerization of dienes

Y Ren, JT Miller, ST Polderman, TD Vo, ACM Wallace… - RSC …, 2019 - pubs.rsc.org
Neodymium-based Ziegler–Natta type catalytic systems are known to produce polydienes
with high cis-1, 4 content. It is generally believed that in Ziegler–Natta catalytic systems, a …

[HTML][HTML] 稀土催化的开环聚合研究进展

沈婷, 倪旭峰, 凌君 - 高分子学报, 2021 - gfzxb.org
稀土催化剂在开环聚合中表现出极高的催化活性, 本文总结了近十年来稀土催化剂在内酯, 交酯,
环醚, 环碳酸酯, 环羧酸酐等单体开环聚合中的应用, 结合催化剂结构与聚合效果总结了稀土 …

Desarrollo de Nuevos Poliésteres Alifáticos de Cristalinidad y Degradación Hidrolítica Controlada Vía Polimerización por Apertura de Anillo (ROP) Utilizando …

GR Durán - 2021 - ciqa.repositorioinstitucional.mx
En la actualidad existe una alta demanda de los materiales denominados “sustentables”,“
biodegradables” o “biobasados”, la cual ha abierto un amplio campo de investigación en la …

Progressive Metal Complex Catalysts for Ring-Opening Polymerization of Cyclic Esters

W Zhang, WH Sun - Synthesis and Applications in Chemistry and …, 2024 - World Scientific
Highly performant and biodegradable polyesters are currently in high-demand as polymeric
materials for sustainable applications. Interestingly, such polymers could be prepared …