The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …

Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

The activation and utilization of substrates mediated by Frustrated Lewis Pairs (FLPs) was
initially believed to occur solely via a two-electron, cooperative mechanism. More recently …

The photoactivation of electron donor‐acceptor complexes has emerged as a sustainable,
selective and versatile strategy for the generation of radical species. Electron donor …

The arylethylamine pharmacophore is conserved across a range of biologically active
natural products and pharmaceuticals, particularly in molecules that act on the central …

Despite the frequent occurrence of sulfonamides in contemporary pharmaceuticals and
agrochemicals, the synthesis of these compounds is limited by the availability of preexisting …

To date,[3+ 2] cycloadditions of diazo esters with alkynes or alkenes have been a robust tool
to generate pyrazoles and pyrazolines. However, methods capable of generating …

Recently, photochemistry of Electron Donor–Acceptor (EDA) complexes employing catalytic
amounts of electron donors have become of interest as a new methodology in the catalysis …

An efficient strategy for the preparation of aryl phosphonates via blue-light-promoted single
electron transfer process of an EDA complex between phosphites and thianthrenium salts …

The formation of carbon–carbon bonds via the intermolecular addition of alkyl radicals to
alkenes is a cornerstone of organic chemistry and plays a central role in synthesis. However …