Formation of the acenaphthylene cation as a common C 2 H 2-loss fragment in dissociative ionization of the PAH isomers anthracene and phenanthrene
Polycyclic aromatic hydrocarbons (PAHs) are thought to be a major constituent of
astrophysical environments, being the carriers of the ubiquitous aromatic infrared bands …
astrophysical environments, being the carriers of the ubiquitous aromatic infrared bands …
The FELion cryogenic ion trap beam line at the FELIX free-electron laser laboratory: infrared signatures of primary alcohol cations
P Jusko, S Brünken, O Asvany, S Thorwirth… - Faraday …, 2019 - pubs.rsc.org
The combination of a 4 K 22-pole ion trap instrument, FELion, with the widely tunable free
electron lasers at the FELIX Laboratory is described in detail. It allows for wide-range …
electron lasers at the FELIX Laboratory is described in detail. It allows for wide-range …
Structural investigation of doubly-dehydrogenated pyrene cations
The vibrationally resolved spectra of the pyrene cation and doubly-dehydrogenated pyrene
cation (C16H10˙+; Py+ and C16H8˙+; ddPy+) are presented. Infrared predissociation …
cation (C16H10˙+; Py+ and C16H8˙+; ddPy+) are presented. Infrared predissociation …
Spectroscopic detection of cyano-cyclopentadiene ions as dissociation products upon ionization of aniline
The H-loss products (C6H6N+) from the dissociative ionization of aniline (C6H7N) have
been studied by infrared predissociation spectroscopy in a cryogenic ion trap instrument at …
been studied by infrared predissociation spectroscopy in a cryogenic ion trap instrument at …
Photodissociation of aliphatic PAH derivatives under relevant astrophysical conditions
Context. The interaction of polycyclic aromatic hydrocarbons (PAHs) with vacuum ultraviolet
(VUV) photons triggers the emission of the well-known aromatic infrared bands (AIBs), but …
(VUV) photons triggers the emission of the well-known aromatic infrared bands (AIBs), but …
Direct Evidence of the Benzylium and Tropylium Cations as the Two Long‐Lived Isomers of C7H7+
P Jusko, A Simon, S Banhatti, S Brünken… - …, 2018 - Wiley Online Library
Disentangling the isomeric structure of C7H7+ is a longstanding experimental issue. We
report here the full mid‐infrared vibrational spectrum of C7H7+ tagged with Ne obtained with …
report here the full mid‐infrared vibrational spectrum of C7H7+ tagged with Ne obtained with …
Infrared spectroscopy of the benzylium-like (and tropylium-like) isomers formed in the–H dissociative ionization of methylated PAHs
G Wenzel, A Simon, S Banhatti, P Jusko… - Journal of Molecular …, 2022 - Elsevier
Cationic benzylium and tropylium are known to be two competitive isomers for the–H
fragment of the methylbenzene (toluene) cation. Methylated polycyclic aromatic hydrocarbon …
fragment of the methylbenzene (toluene) cation. Methylated polycyclic aromatic hydrocarbon …
Dissociation of polycyclic aromatic hydrocarbons at high energy: MD/DFTB simulations versus collision experiments: Fragmentation paths, energy distribution and …
A Simon, JP Champeaux, M Rapacioli… - Theoretical Chemistry …, 2018 - Springer
The whole process following collisions of polycyclic aromatic hydrocarbons (PAHs) with high
energetic protons is modeled and compared to the experimental mass spectrum, allowing to …
energetic protons is modeled and compared to the experimental mass spectrum, allowing to …
Photo-processing of astro-PAHs
Polycyclic aromatic hydrocarbons (PAHs) are key species in astrophysical environments in
which vacuum ultraviolet (VUV) photons are present, such as star-forming regions. The …
which vacuum ultraviolet (VUV) photons are present, such as star-forming regions. The …
Infrared action spectroscopy of doubly charged PAHs and their contribution to the aromatic infrared bands
The so-called aromatic infrared bands (AIBs) are attributed to emission of polycyclic
aromatic hydrocarbons (PAHs). The observed variations toward different regions in space …
aromatic hydrocarbons (PAHs). The observed variations toward different regions in space …