Understanding photodriven multielectron reaction pathways requires the identification and
spectroscopic characterization of intermediates and their excited‐state dynamics, which is …

Enzymatic processes, particularly those capable of performing redox reactions, have
recently been of growing research interest. Substrate specificity, optimal activity at mild …

Two-electron, one-proton reactions of a family of [CoCp (dxpe)(NCCH3)] 2+ complexes (Cp=
cyclopentadienyl, dxpe= 1, 2-bis (di (aryl/alkyl) phosphino) ethane) form the corresponding …

A class of cyclometalated RhIII complexes [Cp* Rh (ppy)(SR)] bearing thiolate ligands, Cp*=
pentamethylcyclopentadienyl, ppy= 2-phenylpyridinate, and R= pyridyl (Spy, 2), pyrimidyl …

A family of cationic cycloplatinated (II) complexes [Pt (dfppy)(P^ P)] Cl incorporating
bisphosphine ligands was prepared:(dfppy= 2-(2, 4-difluorophenyl) pyridine; P^ P= bis …

A rhodaelectro-catalyzed C2–H selectively decarboxylative alkenylation of 3-carboxy-1 H-
indoles employing electricity as the traceless terminal oxidant has been accomplished. The …

This work reports a computational investigation of the effect of ancillary ligands on the
activity of an Rh catalyst for hydrogen evolution based on the [Cp* Rh] motif (Cp*= η5 …

Regeneration of nicotinamide adenine dinucleotide (NADH) has been the primary interest in
the field of enzymatic transformation, especially associating oxidoreductases given the …

In recent years, metal complexes of pyridyl‐mesoionic carbene (MIC) ligands have been
reported as excellent homogeneous and molecular electrocatalysts. In combination with …

In hydrogenation mediated by half-sandwich complexes of Rh, Cp* Rh (III)–H intermediates
are critical hydride-delivery agents. For bipyridine-supported complexes, a unique …