Ligands with phosphorus donor atoms have probably been the most studied ones in
transition metal catalyzed reactions. Because of the recognition of the carbon-metal bonding …

Compounds that contain a late transition metal-nitrogen multiple bond represent important
reactive intermediate species in many useful organic and inorganic transformations. In order …

Nickel PyBox catalysts promote nucleophilic cyclopropanation reactions using CH2Cl2 as a
methylene source and Mn as a stoichiometric reductant. The substrate scope includes a …

Nickel complexes of a PCcarbeneP pincer ligand framework are described.
Dehydrobromination of the precursor (PCsp3P) NiBr in the presence of a donor (PPh3 or …

A sterically accessible tert-butyl-substituted dipyrrinato di-iron (II) complex [(t BuL) FeCl] 2
possessing two bridging chloride atoms was synthesized from the previously reported …

Chemical transformations that result in either the formation or cleavage of carbon–
heteroatom bonds are among the most important processes in the chemical sciences …

Syntheses, properties, and reactivities of nucleophilic phosphinidene complexes [LnM P
R] are reviewed. Emphasis is placed on the electronic tuning of this emerging class of …

The synthesis and structure of the β-diketiminato Ni (I) lutidine adducts [Me x NN] Ni (2, 4-
lutidine)(x= 2 (2); x= 3 (3)) are described which serve as synthons to the “naked” 13-electron …

We report Ti-catalyzed radical formal [3+ 2] cycloadditions of N-acylaziridines and alkenes.
This method provides an efficient approach to the synthesis of pyrrolidines, structural units …

A RhII‐catalyzed direct and stereospecific N‐H‐and N‐alkyl aziridination of olefins is
reported that uses hydroxylamine‐O‐sulfonic acids as inexpensive, readily available, and …